Catalytic cycloaddition of diazo amides to fullerene C60

被引：0

作者：

Tuktarov, A. R. ^{[1
]}

Khuzina, L. L. ^{[1
]}

Dzhemilev, U. M. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Petrochem & Catalysis, Ufa 450075, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2013年 / 62卷 / 01期

关键词：

fullerene C-60; diazo amides; cycloaddition; metal complex catalysis; pyrazolinofullerenes; ALKYL DIAZOACETATES; CHEMISTRY; METHANOFULLERENES; DERIVATIVES; DIAZOALKANES; DIAZOKETONES; FULLEROIDS;

D O I：

10.1007/s11172-013-0014-4

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient catalytic method for cycloaddition of diazo amides to fullerene C-60 in the presence of the three-component catalyst Pd(acac)(2)-PPh3-Et3Al was developed. The yields and selective formation of the target cycloadducts do not depend on the structure of the starting diazo compound.

引用

页码：104 / 106

页数：3

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