Bioleaching waste printed circuit boards by Acidithiobacillus ferrooxidans and its kinetics aspect

被引:109
作者
Yang, Yuankun [1 ]
Chen, Shu [1 ]
Li, Shicheng [2 ]
Chen, Mengjun [1 ]
Chen, Haiyan [1 ]
Liu, Bijun [2 ]
机构
[1] Southwest Univ Sci & Technol, Minist Educ, Key Lab Solid Waste Treatment & Resource Recycle, Mianyang 621010, Peoples R China
[2] China Acad Engn Phys, Inst Nucl Phys & Chem, Mianyang 621900, Peoples R China
关键词
Bioleaching; Waste printed circuit boards; Metal recovery; Acidithiobacillus ferrooxidans; H+ consumption; ELECTRONIC SCRAP; MIXED CULTURE; RECOVERY; METALS; COPPER; OXIDATION; BACTERIA;
D O I
10.1016/j.jbiotec.2014.01.008
中图分类号
Q81 [生物工程学(生物技术)]; Q93 [微生物学];
学科分类号
071005 ; 0836 ; 090102 ; 100705 ;
摘要
In this paper, H+ consumption and metal recovery, during the process of bioleaching waste printed circuit boards (WPCBs) by Acidithiobacillus ferrooxidans (A. ferrooxidans), were discussed in detail. When the WPCBs concentration was 15 g/L, Cu (96.8%), Zn (83.8%), and Al (75.4%) were recovered after 72 h by A. ferrooxidans. Experimental results indicated that metal recovery rate was significantly influenced by acid. Based on experimental results, the kinetics of the H+ consumption and metal recovery on bioleaching WPCBs were represented by reaction kinetic equations. The kinetic of H+ consumption could be described by the second-order kinetic model. The metal recovery belongs to the second-order model with adding acid, which was changed to the shrinking core model with precipitate production. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:24 / 30
页数:7
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