Room temperature CO sensor fabricated from Pt-loaded SnO2 porous nanosolid

被引:84
作者
Wang, Kang [1 ,2 ]
Zhao, Tianyu [1 ]
Lian, Gang [1 ]
Yu, Qinqin [1 ]
Luan, Chunhong [1 ]
Wang, Qilong [2 ]
Cui, Deliang [1 ]
机构
[1] Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
[2] Shandong Univ, Sch Chem & Chem Engn, Educ Minist, Key Lab Special Funct Aggregated Mat, Jinan 250100, Peoples R China
关键词
SnO2 porous nanosolid; Room temperature sensitivity; Pt loading; Response; Selectivity; HALL-EFFECT MEASUREMENTS; GAS SENSOR; SENSING PERFORMANCE; CARBON-MONOXIDE; SURFACE; OXIDATION; DEPOSITION; ADDITIVES; CATALYSTS;
D O I
10.1016/j.snb.2013.04.054
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Highly sensitive room temperature carbon monoxide (CO) gas sensor was prepared by Pt-loaded SnO2 porous nanosolid (SnO2:Pt PNS). The effects of preparation conditions on sensor response were studied and the highest response to 100 ppm CO at room temperature reached a value of 64.5, which is actually high compared with previous reports. In addition, SnO2: Pt PNS sensor showed a good CO selectivity against H-2. Hall effect measurement was conducted to analyze the sensing mechanism, which reveals that SnO2 PNS is highly depleted after Pt-loading and the high response of our sensors depends on the change of both electron concentration and mobility upon exposing to CO gas. The sensor response is also favored by the highly porous, interconnected small-grain structure of SnO2 PNS. (c) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:33 / 39
页数:7
相关论文
共 44 条
[1]   Sol-gel derived thin-film semiconductor hydrogen gas sensor [J].
Adamyan, A. Z. ;
Adamyan, Z. N. ;
Aroutiounian, V. M. ;
Arakelyan, A. H. ;
Touryan, K. J. ;
Turner, J. A. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2007, 32 (16) :4101-4108
[2]   The surface and materials science of tin oxide [J].
Batzill, M ;
Diebold, U .
PROGRESS IN SURFACE SCIENCE, 2005, 79 (2-4) :47-154
[3]   OXIDATION OF CARBON-MONOXIDE ON PLATINUM TIN DIOXIDE CATALYSTS AT LOW-TEMPERATURES [J].
BOULAHOUACHE, A ;
KONS, G ;
LINTZ, HG ;
SCHULZ, P .
APPLIED CATALYSIS A-GENERAL, 1992, 91 (02) :115-123
[4]   Analysis of the noble metal catalytic additives introduced by impregnation of as obtained SnO2 sol-gel nanocrystals for gas sensors [J].
Cabot, A ;
Arbiol, J ;
Morante, JR ;
Weimar, U ;
Bârsan, N ;
Göpel, W .
SENSORS AND ACTUATORS B-CHEMICAL, 2000, 70 (1-3) :87-100
[5]   Room temperature CO sensing of selectively grown networked ZnO nanowires by Pd nanodot functionalization [J].
Choi, Sun-Woo ;
Kim, Sang Sub .
SENSORS AND ACTUATORS B-CHEMICAL, 2012, 168 :8-13
[6]   Sensing properties of SnO2-Co3O4 composites to CO and H2 [J].
Choi, US ;
Sakai, G ;
Shimanoe, K ;
Yamazoe, N .
SENSORS AND ACTUATORS B-CHEMICAL, 2004, 98 (2-3) :166-173
[7]   SPILLOVER IN HETEROGENEOUS CATALYSIS [J].
CONNER, WC ;
FALCONER, JL .
CHEMICAL REVIEWS, 1995, 95 (03) :759-788
[8]   Homogeneous coating of Au and SnO2 nanocrystals on carbon nanotubes via layer-by-layer assembly: a new ternary hybrid for a room-temperature CO gas sensor [J].
Du, Ning ;
Zhang, Hui ;
Ma, Xiangyang ;
Yang, Deren .
CHEMICAL COMMUNICATIONS, 2008, (46) :6182-6184
[9]   Hall effect measurements in gas sensors based on nanosized Os-doped sol-gel derived SnO2 thin films [J].
Epifani, M ;
Forleo, A ;
Capone, S ;
Quaranta, F ;
Rella, R ;
Siciliano, P ;
Vasanelli, L .
IEEE SENSORS JOURNAL, 2003, 3 (06) :827-834
[10]   CHARACTERIZATION STUDY OF SILICA-SUPPORTED PLATINIZED TIN OXIDE CATALYSTS USED FOR LOW-TEMPERATURE CO OXIDATION - EFFECT OF PRETREATMENT TEMPERATURE [J].
GARDNER, SD ;
HOFLUND, GB ;
SCHRYER, DR ;
UPCHURCH, BT .
JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (02) :835-838