Palladium(II) and platinum(II) pyrrolate-quinoline-imine chloro-complexes by metal-assisted condensation reactions

被引：2

作者：

Bortoluzzi, Marco ^{[1
,2
]}

Agostinis, Lodovico ^{[1
]}

Bertolasi, Valerio ^{[3
,4
]}

机构：

[1] Univ Ca Foscari Venezia, Dipartimento Sci Mol & Nanosistemi, Via Torino 155, I-30170 Venice, VE, Italy

[2] Consorzio Interuniv Reatt Chim & Catalisi CIRCC, Via Celso Ulpiani 27, I-70126 Bari, Italy

[3] Univ Ferrara, Dipartimento Sci Chim & Farmaceut, Via L Borsari 46, I-44100 Ferrara, Italy

[4] Univ Ferrara, Ctr Strutturist Diffrattometr, Via L Borsari 46, I-44100 Ferrara, Italy

来源：

CHEMICAL PAPERS | 2020年 / 74卷 / 11期

关键词：

Palladium(II); Platinum(II); N-donor ligands; Metal-assisted synthesis; SOLVENT-INDUCED AGGREGATION; SUPRAMOLECULAR RECOGNITION; MOLECULAR RECOGNITION; TERPYRIDINE COMPLEXES; CRYSTAL-STRUCTURE; PT(II) COMPLEXES; CYTOCHROMES-C; LIGANDS; ASSOCIATION; CLEFTS;

D O I：

10.1007/s11696-019-00753-6

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Neutral palladium(II) and platinum(II) chloro-complexes with the conjugate base of [(pyrrol-2-yl)methylene]quinolin-8-amine were prepared in a single step by reacting 8-aminoquinoline and pyrrole-2-aldehyde with [MCl(CH3)(COD)] (M = Pd, Pt; COD = 1,5-cyclooctadiene). The reaction consists of a metal-assisted condensation and the protonolysis of the M-C bond by the pyrrole NH. The solid-state structure of the palladium derivative was determined by X-ray diffraction, while the electronic features of the complexes were investigated by means of DFT calculations.

引用

页码：3673 / 3682

页数：10

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