Copper-catalyzed C-Se coupling of diphenyl diselenide with arylboronic acids at room temperature

被引：51

作者：

Zheng, Bo ^{[1
]}

Gong, Ying ^{[1
]}

Xu, Hua-Jian ^{[1
]}

机构：

[1] Hefei Univ Technol, Sch Med Engn, Key Lab Adv Funct Mat & Devices, Hefei 230009, Anhui Province, Peoples R China

来源：

TETRAHEDRON | 2013年 / 69卷 / 26期

基金：

中国国家自然科学基金;

关键词：

C-Se coupling; Copper-catalyzed; Diphenyl diselenide; Arylboronic acids; Room temperature; BORONIC ACIDS; DITELLURIDES; ARYLATION; SELENIDES;

D O I：

10.1016/j.tet.2013.04.124

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient synthetic protocol for the Cu-catalyzed cross-coupling of diphenyl diselenide and arylboronic acid at room temperature was described. This catalytic system could tolerate a variety of arylboronic acids with only 3 mol % amount of CuSO4 as the catalyst and inexpensive 1,10-phen. H2O as the ligand. Moreover, this catalytic system used environment-friendly EtOH as the solvent and catalytic amount of Na2CO3 (20 mol %) as the base in the air. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：5342 / 5347

页数：6

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