Complex atomic dynamics in a deep-eutectic binary metallic melt

被引:8
作者
Chathoth, S. M. [1 ]
Koza, M. M. [2 ]
Meyer, A. [3 ]
机构
[1] Tech Univ Munich, Phys Dept E13, D-85747 Garching, Germany
[2] Inst Max Von Laue Paul Langevin, F-38042 Grenoble, France
[3] Deutsch Zentrum Luft & Raumfahrt DLR, Inst Mat Phys Weltraum, D-51170 Cologne, Germany
关键词
Quasielastic neutron scattering; Metallic melts; Diffusion; Mode-Coupling Theory; GLASS FORMATION; RELAXATION; DIFFUSION; ALLOYS; LIQUID;
D O I
10.1016/j.matchemphys.2012.07.011
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Quasielastic neutron scattering (QENS) was used to explore relaxation processes in a deep-eutectic Ce80Ni20 melt over a temperature range of 750 K, i.e., from 775 K to 1525 K. At low temperatures (T <= 890 K), the self-correlation function shows a fast beta-relaxation process. The alpha-relaxation process displays stretching of the self-correlation and obeys a time temperature superposition principle that extends over the entire measured temperature range. Even though the decay of the self-correlation functions of the Ce80Ni20 melt exhibit that of glass-forming melts, the temperature dependence of self-diffusivity displays an Arrhenius behavior, as observed for many simple, non-glass forming liquids. Published by Elsevier B.V.
引用
收藏
页码:296 / 299
页数:4
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