Pyridinium dichlorobromate: A new stable brominating agent for aromatic compounds

被引:0
作者
Muathen, HA [1 ]
机构
[1] Umm Al Qura Univ, Dept Chem, Mecca, Saudi Arabia
来源
SYNTHESIS-STUTTGART | 2002年 / 02期
关键词
pyridinium dichlorobromate; bromination; bromine chloride; aromatic compounds;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Pyridinium dichlorobromate (PyHBrCl2, 1) is a new example of iminium-trihalide complexes. The compound is prepared from pyridine and chlorine in the presence of aqueous hydrogen bromide. The crystalline trihalide is quite stable and acts as a safe source of positive bromine. It shows a remarkable reactivity towards aromatic compounds compared with other bromine complexes. It is also considered as a potential source for bromine c or e BrCl.
引用
收藏
页码:169 / 171
页数:3
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