Lithium perchlorate-catalysed rearrangement of 1-methylcyclohex-2-enylhydroperoxide into 2-methylenecyclohexylhydroperoxide

被引：1
作者：
Kinart, Wojciech J. [1 ]
Kinart, Andrzej [1 ]
Sendecki, Marcin [1 ]
机构：
[1] Univ Lodz, Dept Organ Chem, PL-90131 Lodz, Narutowicza, Poland
来源：
PHYSICS AND CHEMISTRY OF LIQUIDS | 2008年 / 46卷 / 06期
关键词：
1-methyl-1-cyclohexene; photochemical oxidation; lithium perchlorate; rearrangements of hydroperoxides; homogenous catalysis;
D O I：
10.1080/00319100802072656
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The catalytic effect of 5 mol dm-3 solution of LiClO4 in Et2O on the rearrangement of 1-methylcyclohex-2-enylhydroperoxide into 2-methylenecyclohexylhydroperoxide has been observed.
引用
收藏
页码：627 / 630
页数：4
相关论文
共 23 条
  • [1] An anion-dependent switch in selectivity results from a change of C-H activation mechanism in the reaction of an imidazolium salt with IrH5(PPh3)2
    Appelhans, LN
    Zuccaccia, D
    Kovacevic, A
    Chianese, AR
    Miecznikowski, JR
    Macchioni, A
    Clot, E
    Eisenstein, O
    Crabtree, RH
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (46) : 16299 - 16311
  • [2] Crucial role of anions on the deprotonation of the cationic dihydrogen complex trans-[FeH(η2-H2)(dppe)2]+
    Basallote, Manuel G.
    Besora, Maria
    Castillo, C. Esther
    Fernandez-Trujillo, Maria J.
    Lledos, Agusti
    Maseras, Feliu
    Manez, M. Angeles
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (20) : 6608 - 6618
  • [3] A THEORETICAL INVESTIGATION OF THE 1,3-MIGRATION IN ALLYLPEROXYL RADICALS
    BOYD, SL
    BOYD, RJ
    SHI, Z
    BARCLAY, LRC
    PORTER, NA
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (02) : 687 - 693
  • [4] ISOLATION AND REARRANGEMENT OF PURE ACYCLIC ALLYLIC HYDROPEROXIDES
    BRILL, WF
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (14) : 3286 - &
  • [5] THE ALLYLIC REARRANGEMENT OF HYDROPEROXIDES - THE ALLYLPEROXYL RADICAL
    BRILL, WF
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1984, (04): : 621 - 627
  • [6] INITIATED TERT-BUTYL HYDROPEROXIDE-LOADED LOW-TEMPERATURE AUTOXIDATION OF ALKENES - ALTERNATIVE HYDROPEROXIDE SYNTHESES AND THE PREPARATION OF A COMPLETE SET OF REFERENCE MATERIALS
    COURTNEIDGE, JL
    BUSH, M
    LOH, LS
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1992, (12): : 1539 - 1548
  • [7] DAVIES AG, 1989, J CHEM RES-S, P22
  • [8] CATALYSIS OF ENE REACTIONS BY LITHIUM PERCHLORATE
    DAVIES, AG
    KINART, WJ
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1993, (11): : 2281 - 2284
  • [9] DAVIES AG, 1989, J CHE SOC P2, P815
  • [10] Computational study of the mechanism of cyclometalation by palladium acetate
    Davies, DL
    Donald, SMA
    Macgregor, SA
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (40) : 13754 - 13755
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