Synthesis of optically active Zn(II) complexes with thiosemicarbazones of (+)-camphor (L) and (-)-carvone (L1). The crystal structures of L and [Zn(L)2Cl2]

被引：5

作者：

Kokina, T. E. ^{[1
,2
]}

Gorshkov, N. B. ^{[2
,3
]}

Glinskaya, L. A. ^{[1
]}

Kurat'eva, N. V. ^{[1
]}

Sheludyakova, L. A. ^{[1
]}

Tkachev, A. V. ^{[2
,3
]}

Larionov, S. V. ^{[1
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia

[2] Novosibirsk State Univ, Novosibirsk 630090, Russia

[3] Russian Acad Sci, Vorozhtsov Inst Organ Chem, Siberian Branch, Novosibirsk, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2013年 / 39卷 / 06期

关键词：

TRANSITION-METAL COMPLEXES; ANTITUMOR-ACTIVITY; ANTIFUNGAL;

D O I：

10.1134/S1070328413050035

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The optically active complexes [Zn(L)(2)Cl-2] (I) and [Zn(L-1)(2)Cl-2] (II) (L and L-1 are thiosemicar-bazones of (+)-camphor and (-)-carvone, respectively) were obtained. The crystal structures of L and complex I were determined by X-ray diffraction. The structure of L consists of hydrogen-bonded molecules united into chains. The crystal structure of complex I is built from mononuclear molecules. The coordination polyhedron of the Zn atom is a distorted tetrahedron Cl2S2. The molecule L functions as a monodentate ligand. According to data from IR spectroscopy, complex II is structurally similar to complex I.

引用

页码：442 / 449

页数：8

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