Role of film thickness on the properties of ZnO thin films grown by sol-gel method

被引:168
作者
Kumar, Vinod [1 ,2 ,6 ]
Singh, Neetu [3 ,4 ]
Mehra, R. M. [5 ]
Kapoor, Avinashi [3 ]
Purohit, L. P. [2 ]
Swart, H. C. [6 ]
机构
[1] Inter Univ Accelerator Ctr, Mat Sci Grp, New Delhi 110067, India
[2] Gurukula Kangri Univ, Dept Phys, Haridwar 249404, India
[3] Univ Delhi, Dept Elect Sci, New Delhi 110021, India
[4] Univ Delhi, Keshav Mahavidyalaya, Dept Elect, Delhi 110034, India
[5] Sharda Univ, Sch Engn & Technol, Greater Noida 201306, India
[6] Univ Orange Free State, Dept Phys, ZA-9300 Bloemfontein, South Africa
关键词
Sol-gel; Zinc oxide; Thickness; Surface morphology; Solar cell and gas sensors; OPTICAL-PROPERTIES;
D O I
10.1016/j.tsf.2013.05.088
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This paper reports the effect of thickness on the structural, morphological and optical properties of zinc oxide (ZnO) films. Thickness of ZnO films varied from 98 to 366 nm with an increase in the number of deposition cycles. Surface morphological studies showed that the increase in the film thickness causes an increase in the grain size. Roughness of the films has increased from 5.8 to 47 nm with an increase in the film thickness from 98 to 366 nm. The band gap is observed to vary from 3.33 to 3.24 eV with change in the film thickness from 98 to 366 nm. Thickness of the film affected the overall properties of the ZnO films significantly. The large surface roughness makes ZnO films to be potentially used as electrode in solar cells and gas sensing applications. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:161 / 165
页数:5
相关论文
共 33 条
[1]   Zinc oxide nanorods grown on two-dimensional macroporous periodic structures and plane Si as a pH sensor [J].
Al-Hilli, Safaa M. ;
Al-Mofarji, R. T. ;
Klason, P. ;
Willander, M. ;
Gutman, N. ;
Sa'ar, A. .
JOURNAL OF APPLIED PHYSICS, 2008, 103 (01)
[2]   Fundamental structure forming phenomena of polycrystalline films and the structure zone models [J].
Barna, PB ;
Adamik, M .
THIN SOLID FILMS, 1998, 317 (1-2) :27-33
[3]   ELASTIC MODULI OF SINGLE-CRYSTAL ZINC OXIDE [J].
BATEMAN, TB .
JOURNAL OF APPLIED PHYSICS, 1962, 33 (11) :3309-&
[4]   Microstructure and photovoltaic performance of polycrystalline silicon thin films on temperature-stable ZnO:Al layers [J].
Becker, C. ;
Ruske, F. ;
Sontheimer, T. ;
Gorka, B. ;
Bloeck, U. ;
Gall, S. ;
Rech, B. .
JOURNAL OF APPLIED PHYSICS, 2009, 106 (08)
[5]   Effects of annealing on photoluminescence of ZnO thin film prepared by vapor phase growth [J].
Chen, J ;
Fujita, T .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2003, 42 (2A) :602-606
[6]   Nanowire nanosensors for highly sensitive and selective detection of biological and chemical species [J].
Cui, Y ;
Wei, QQ ;
Park, HK ;
Lieber, CM .
SCIENCE, 2001, 293 (5533) :1289-1292
[7]   CONDUCTION IN NON-CRYSTALLINE SYSTEMS .5. CONDUCTIVITY, OPTICAL ABSORPTION AND PHOTOCONDUCTIVITY IN AMORPHOUS SEMICONDUCTORS [J].
DAVIS, EA ;
MOTT, NF .
PHILOSOPHICAL MAGAZINE, 1970, 22 (179) :903-&
[8]   Indium phosphide nanowires as building blocks for nanoscale electronic and optoelectronic devices [J].
Duan, XF ;
Huang, Y ;
Cui, Y ;
Wang, JF ;
Lieber, CM .
NATURE, 2001, 409 (6816) :66-69
[9]   ZnO thin films preparation by spray pyrolysis and electrical characterization [J].
Goyal, Ankit ;
Kachhwaha, S. .
MATERIALS LETTERS, 2012, 68 :354-356
[10]   TEXTURED ALUMINUM-DOPED ZINC-OXIDE THIN-FILMS FROM ATMOSPHERIC-PRESSURE CHEMICAL-VAPOR DEPOSITION [J].
HU, JH ;
GORDON, RG .
JOURNAL OF APPLIED PHYSICS, 1992, 71 (02) :880-890