Cross-Coupling Reactions Involving Metal Carbene: From C=C/C-C Bond Formation to C-H Bond Functionalization

被引：217
作者：
Liu, Zhenxing [1 ]
Wang, Jianbo [1 ,2 ]
机构：
[1] Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, BNLMS,Minist Educ, Beijing 100871, Peoples R China
[2] Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2013年 / 78卷 / 20期
关键词：
PALLADIUM-CATALYZED INSERTION; N-TOSYLHYDRAZONES; DIAZO-COMPOUNDS; VINYL HALIDES; ARYL IODIDES; ALKYLATION; ACTIVATION; REAGENTS; ETHERS;
D O I：
10.1021/jo401850q
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Cross-coupling reactions involving metal-carbene are emerging as a new type of carbon-carbon bond-forming reaction. The aim of this JOCSynopsis is to provide an overview of the most recent development of these reactions, focusing on the use of diazo compounds (or in situ formed diazo compounds from N-tosylhydrazones) as carbene precursors. In addition, the integration of this type of reaction with C-H bond functionalization is also surveyed.
引用
收藏
页码：10024 / 10030
页数：7
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