Fabrication and Microwave Dielectric Properties of Mg2SiO4-LiMgPO4-TiO2 Composite Ceramics

被引:17
作者
Cheng, ZiFan [1 ]
Hu, Xing [1 ]
Li, Yi [1 ]
Ling, ZhiYuan [1 ]
机构
[1] South China Univ Technol, Dept Elect Mat Sci & Engn, Guangzhou 510640, Peoples R China
关键词
microwave dielectrics; forsterite; LiMgPO4; TEMPERATURE; FORSTERITE; LIMGPO4; MG2SIO4;
D O I
10.1111/jace.14276
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Complete solid solutions between Mg2SiO4 and LiMgPO4 are confirmed by the XRD results. The phase constitution of 0.5Mg(2)SiO(4)-0.5LiMgPO(4) is found to be dependent on firing temperature. The chemical compatibility between Mg2SiO4 and rutile phase at sintering temperature is modified by incorporating LiMgPO4. The microwave dielectric properties of (1 - y)(0.5Mg(2)SiO(4)-0.5LiMgPO(4))-yTiO(2) (y = 0-0.3) composite ceramics have been investigated. The optimized microwave dielectric properties for 0.35Mg(2)SiO(4)-0.35LiMgPO(4)-0.3TiO(2) ceramics sintered at 1050 degrees C show low dielectric constant (11.4), high-quality factor (31 800 GHz), and low-temperature coefficient of resonant frequency (-4 ppm/degrees C).
引用
收藏
页码:2688 / 2692
页数:5
相关论文
共 23 条
[1]   Sintered alumina with low dielectric loss [J].
Alford, NM ;
Penn, SJ .
JOURNAL OF APPLIED PHYSICS, 1996, 80 (10) :5895-5898
[2]   Dielectric properties of magnesium oxide at microwave frequency [J].
Chen, Jhih-Yong ;
Hsu, Wei-Hung ;
Huang, Cheng-Liang .
JOURNAL OF ALLOYS AND COMPOUNDS, 2010, 504 (01) :284-287
[3]   LTCC glass-ceramic composites for microwave application [J].
Dernovsek, O ;
Naeini, A ;
Preu, G ;
Wersing, W ;
Eberstein, M ;
Schiller, WA .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2001, 21 (10-11) :1693-1697
[4]   Low-temperature sintered Mg2SiO4-CaTiO3 ceramics with near-zero temperature coefficient of resonant frequency [J].
Dou, Gang ;
Zhou, Dongxiang ;
Guo, Mei ;
Gong, Shuping ;
Hu, Yunxiang .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2013, 24 (05) :1431-1438
[5]   Low-Temperature Sintering and Microwave Dielectric Properties of Li2MgSiO4 Ceramics [J].
George, Sumesh ;
Anjana, Prabhakaran Sreekumari ;
Deepu, Vasudevan Nair ;
Mohanan, Pezholil ;
Sebastian, Mailadil Thomas .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2009, 92 (06) :1244-1249
[6]   Characterization and dielectric behavior of willemite and TiO2-doped willemite ceramics at millimeter-wave frequency [J].
Guo, YP ;
Ohsato, H ;
Kakimoto, KI .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2006, 26 (10-11) :1827-1830
[7]   CRYSTAL-STRUCTURE OF LITHIUM MAGNESIUM PHOSPHATE, LIMGPO4 - CRYSTAL-CHEMISTRY OF THE OLIVINE-TYPE COMPOUNDS [J].
HANIC, F ;
HANDLOVIC, M ;
BURDOVA, K ;
MAJLING, J .
JOURNAL OF CRYSTALLOGRAPHIC AND SPECTROSCOPIC RESEARCH, 1982, 12 (02) :99-127
[8]   Mg2SiO4-TiO2 composite ceramics prepared using a liquid phase deposition process [J].
Kagomiya, I. ;
Sugihara, J. ;
Kakimoto, K. ;
Ohsato, H. .
JOURNAL OF ELECTROCERAMICS, 2009, 22 (1-3) :327-333
[9]   Electron density distribution and bond critical point properties for forsterite, Mg2SiO4, determined with synchrotron single crystal X-ray diffraction data [J].
Kirfel, A ;
Lippmann, T ;
Blaha, P ;
Schwarz, K ;
Cox, DF ;
Rosso, KM ;
Gibbs, GV .
PHYSICS AND CHEMISTRY OF MINERALS, 2005, 32 (04) :301-313
[10]   Microwave Dielectric Properties of Ba3(VO4)2-Mg2SiO4 Composite Ceramics [J].
Meng, Siqin ;
Yue, Zhenxing ;
Zhuang, Hao ;
Zhao, Fei ;
Li, Longtu .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2010, 93 (02) :359-361