Selective and efficient hydrocarbon oxidation in a packed bed membrane reactor

被引：5

作者：

Langhendries, G

Baron, GV

Jacobs, PA

机构：

[1] Free Univ Brussels, Dept Chem Engn, B-1050 Brussels, Belgium

[2] Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, B-3001 Heverlee, Belgium

来源：

CHEMICAL ENGINEERING SCIENCE | 1999年 / 54卷 / 10期

关键词：

selective oxidation; packed bed membrane reactor; modeling;

D O I：

10.1016/S0009-2509(99)00063-9

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The liquid phase hydrocarbon oxidation is studied in a packed bed membrane reactor. A mathematical model is developed, reaction simulations are performed and interpreted using the conversion, organic peroxide efficiency and oxidation product separation factor. The influence of several process parameters, such as space time, overall membrane mass transfer coefficient and aqueous-organic phase distribution coefficient is investigated. A substantial increase in organic peroxide efficiency was observed in the packed bed membrane reactor configuration as compared to a conventional packed bed reactor. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：1467 / 1472

页数：6

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