Silane/MoO2Cl2 as an efficient system for the reduction of esters

被引：104

作者：

Fernandes, Ana C. ^{[1
]}

Romao, Carlos C. ^{[1
]}

机构：

[1] Univ Nova Lisboa, Inst Tecnol Quim & Biol, EAN, P-2781901 Oeiras, Portugal

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2006年 / 253卷 / 1-2期

关键词：

reduction; esters; dioxomolybdenum dichloride; silanes;

D O I：

10.1016/j.molcata.2006.03.006

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The first method for the reduction of esters using a high oxidation state oxo complex as a catalyst is reported. The system silane/MoO2Cl2 (5 mol%) proved to be very efficient for the reduction of aliphatic and aromatic esters to the corresponding alcohols in good yields. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：96 / 98

页数：3

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