An aromatic-antiaromatic switch in P-heteroles.: A small change in delocalisation makes a big reactivity difference

被引：70
作者：
Nyulászi, L
Hollóczki, O
Lescop, C
Hissler, M
Réau, R
机构：
[1] Budapest Univ Technol & Econ, Dept Inorgan Chem, H-1521 Budapest, Hungary
[2] Univ Rennes 1, CNRS, UMR 6509, Inst Chim, F-35042 Rennes, France
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2006年 / 4卷 / 06期
关键词：
D O I：
10.1039/b516836h
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The low aromaticity of phosphole can be switched to low antiaromaticity by oxidizing the phosphorus atom. This subtle change in the mode of delocalisation alters substantially the chemical behaviour of these heteroles.
引用
收藏
页码：996 / 998
页数：3
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