Effect of laser power on orientation and microstructure of Ba2TiO4 film prepared by laser chemical vapor deposition

被引:1
作者
Guo, Dongyun [1 ,2 ,3 ]
Goto, Takashi [1 ]
Wang, Chuanbin [2 ,3 ]
Shen, Qiang [2 ,3 ]
Zhang, Lianmeng [2 ,3 ]
机构
[1] Tohoku Univ, Inst Mat Res, Sendai, Miyagi 9808577, Japan
[2] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Peoples R China
[3] Wuhan Univ Technol, Sch Mat Sci & Engn, Wuhan 430070, Peoples R China
关键词
Ba2TiO4; film; Laser chemical vapor deposition; Orientation; Laser power; BARIUM ORTHOTITANATE; DIELECTRIC-PROPERTIES;
D O I
10.1016/j.apsusc.2012.04.104
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ba2TiO4 films were prepared on Pt/Ti/SiO2/Si substrates by laser chemical vapor deposition method. The effect of laser power (P-L) on orientation and microstructure was investigated. With increasing PL from 52 to 93 W, the deposition temperature (T-dep) increased from 845 to 946 K. With increasing T-dep from 845 to 927 K, the preferred orientation of Ba2TiO4 films changed from (0 9 1) to (1 0 3), the surface morphologies changed from faceted to rectangular, and the columnar cross-section became thicker. The films prepared at high T-dep (931-946 K) had the porous cross-section consisted of powder-like grains. Ba2TiO4 film prepared at 881 K had high deposition rate (R-dep) of 51.4 mu m h(-1), which was advantageous to industrial production. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:7860 / 7863
页数:4
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