Tetraphenylphosphonium triiodide

被引：7

作者：

Parvez, M

Wang, M

Boorman, PM

机构：

[1] Department of Chemistry, University of Calgary, Calgary, Alta. T2N 1N4

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270195010456

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystals of the title compound, C24H20P+.I-3(-), are composed of slightly bent I-3(-) anions and Ph(4)P(+) cations separated by normal van der Waals distances; both ions lie on twofold axes. The I-I distances in the anion are 2.9180 (4) Angstrom, with an I-I-I angle of 175.27 (3)degrees. In the cation, the P-C distances are identical [1.790 (4) Angstrom] and the C-P-C angles are in the range 105.5 (3)-111.6 (2)degrees.

引用

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页码：377 / 378

页数：2

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