Synthesis, Characterization, and Crystal Structures of Copper(II) and Zinc(II) Complexes Derived From the Tridentate Schiff Bases 2-[1-(pyridin-2-ylmethylimino) ethyl] phenol and (1-pyridin-2-ylethylidene)pyridin-2-ylmethylamine

被引：4

作者：

Shi, Da-Hua ^{[1
,2
]}

Cao, Zhi-Ling ^{[1
]}

Liu, Wei-Wei ^{[1
]}

Xu, Rui-Bo ^{[1
]}

Gao, Liu-Liu ^{[1
]}

Zhang, Qian ^{[1
]}

机构：

[1] Huaihai Inst Technol, Sch Chem Engn, Lianyungang 222005, Peoples R China

[2] Huaihai Inst Technol, Jiangsu Key Lab Marine Biotechnol, Lianyungang 222005, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2012年 / 42卷 / 06期

关键词：

copper; crystal structure; Schiff base; synthesis; zinc; UREASE INHIBITORY-ACTIVITIES; BRIDGES; NI(II); MONO;

D O I：

10.1080/15533174.2011.618483

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A centrosymmetric phenolate oxygen bridged dinuclear copper(II) complex [Cu-2(L-1)(2)(N-3)(2)] (1) and a mononuclear zinc(II) complex [Zn(L-2)(NCS)(2)] (2), where HL1 = 2-[1(pyridin-2-ylmethylimino)ethyl]phenol and L-2 = (1-pyridin-2-ylethylidene)pyridin-2-ylmethylamine, were synthesized and structurally characterized by physicochemical methods and single-crystal X-ray diffraction. The Cu atom in (1) is five-coordinated in a slightly distorted square pyramidal geometry, and the Zn atom in (2) is five-coordinated in a severely distorted square pyramidal geometry.

引用

页码：864 / 867

页数：4

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