Stable metal-organic frameworks with high catalytic performance in the cycloaddition of CO2 with aziridines

被引：26
作者：
Kang, Xiao-Min [1 ,2 ]
Shi, Ying [1 ,2 ]
Cao, Chun-Shuai [1 ,2 ]
Zhao, Bin [1 ,2 ]
机构：
[1] Nankai Univ, Coll Chem, Tianjin 300071, Peoples R China
[2] Nankai Univ, Key Lab Adv Energy Mat Chem, Tianjin 300071, Peoples R China
来源：
SCIENCE CHINA-CHEMISTRY | 2019年 / 62卷 / 05期
基金：
中国国家自然科学基金;
关键词：
MOFs; stability; catalysis; oxazolidinones; CO2; conversion; CHEMICAL FIXATION; LUMINESCENT PROBE; CARBON-DIOXIDE; EFFICIENT; CONVERSION; CAPTURE; MOF; CLUSTER; ACETYLACETONE; DRIVEN;
D O I：
10.1007/s11426-018-9420-6
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Based on the mixed ligands XN (4-(4-pyridine)4,2:2,4-terpyridine) and isophthalic acid (IPA), three new metal-organic frameworks (MOFs) {[M-2(XN)(2)(IPA)(2)]center dot 2H(2)O}(n) (M=Co (1), Mn (2), Ni (3)) were assembled and structurally characterized, presenting 3D pillar-chain feature structures. Stability measurements demonstrate that these compounds possess high thermostability and can endure different organic solvents as well as various acid/base solutions with pH range of 1 to 14. Importantly, compounds 1-3 can serve as high-efficiency catalysts for the transformation of CO2 and aziridines to form high-value oxazolidinones under mild conditions, exhibiting excellent cyclicity at least five times.
引用
收藏
页码：622 / 628
页数：7
相关论文
共 47 条
[1]   Assembly of Cadmium(II)-Terpyridine Coordination Frameworks by Different Multicarboxylate Ancillary Ligands [J].
An, Dao-Li ;
Chen, Yong-Qiang ;
Tian, Yuan .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2014, 640 (8-9) :1776-1781
[2]   Synthetic preparation of N-methyl-α-amino acids [J].
Aurelio, L ;
Brownlee, RTC ;
Hughes, AB .
CHEMICAL REVIEWS, 2004, 104 (12) :5823-5846
[3]   Oxazolidinone structure-activity relationships leading to linezolid [J].
Barbachyn, MR ;
Ford, CW .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (18) :2010-2023
[4]   A Hafnium-Based Metal Organic Framework as an Efficient and Multifunctional Catalyst for Facile CO2 Fixation and Regioselective and Enantioretentive Epoxide Activation [J].
Beyzavi, M. Hassan ;
Klet, Rachel C. ;
Tussupbayev, Samat ;
Borycz, Joshua ;
Vermeulen, Nicolaas A. ;
Cramer, Christopher J. ;
Stoddart, J. Fraser ;
Hupp, Joseph T. ;
Farha, Omar K. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (45) :15861-15864
[5]   A multifunctional MOF as a recyclable catalyst for the fixation of CO2 with aziridines or epoxides and as a luminescent probe of Cr(VI) [J].
Cao, Chun-Shuai ;
Shi, Ying ;
Xu, Hang ;
Zhao, Bin .
DALTON TRANSACTIONS, 2018, 47 (13) :4545-4553
[6]   Unusual Magnetic Behaviors and Electronic Configurations Driven by Diverse Co(II) or Mn(II) MOF Architectures [J].
Celeste Bernini, Maria ;
Romero de Paz, Julio ;
Snejko, Natalia ;
Saez-Puche, Regino ;
Gutierrez-Puebla, Enrique ;
Angeles Monge, Maria .
INORGANIC CHEMISTRY, 2014, 53 (24) :12885-12895
[7]   Water-Insoluble Heterometal-Oxide-Based Photocatalysts Effective for the Photo-Decomposition of Methyl Orange [J].
Chen, Yong-Qang ;
Li, Guo-Rong ;
Qu, Yang-Kun ;
Zhang, Ying-Hui ;
He, Kun-Huan ;
Gao, Qiang ;
Bu, Xian-He .
CRYSTAL GROWTH & DESIGN, 2013, 13 (02) :901-907
[8]   Ni-Catalyzed Carboxylation of C(sp2)- and C(sp3)-O Bonds with CO2 [J].
Correa, Arkaitz ;
Leon, Thierry ;
Martin, Ruben .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (03) :1062-1069
[9]   Multipoint Interactions Enhanced CO2 Uptake: A Zeolite-like Zinc-Tetrazole Framework with 24-Nuclear Zinc Cages [J].
Cui, Ping ;
Ma, Yu-Guang ;
Li, Huan-Huan ;
Zhao, Bin ;
Li, Jian-Rong ;
Cheng, Peng ;
Balbuena, Perla B. ;
Zhou, Hong-Cai .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (46) :18892-18895
[10]   Bifunctional lmidazolium-Based Ionic Liquid Decorated UiO-67 Type MOF for Selective CO2 Adsorption and Catalytic Property for CO2 Cycloaddition with Epoxides [J].
Ding, Luo-Gang ;
Yao, Bing-Jian ;
Jiang, Wei-Ling ;
Li, Jiang-Tao ;
Fu, Qi-Juan ;
Li, Yan-An ;
Liu, Zhen-Hua ;
Ma, Jian-Ping ;
Dong, Yu-Bin .
INORGANIC CHEMISTRY, 2017, 56 (04) :2337-2344
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