Preparation and reactions of rhodium complexes of some alkynylamines

被引：28

作者：

Campi, EM

Jackson, WR

机构：

[1] Department of Chemistry, Monash University, Clayton

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 523卷 / 02期

基金：

澳大利亚研究理事会;

关键词：

rhodium; nickel; alkynylamines; rearrangement; stoichiometric complexes; catalysis;

D O I：

10.1016/0022-328X(96)06377-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of [Rh(CO)(2)Cl](2) with the alkynylamines Ph(sic)(CH2)(2)NH2 1 and p-MeC(6)H(4)(sic)(CH2)(3)NH2 2 give the corresponding alkynylamine dicarbonyl rhodium(1) chloride complexes 3 and 4 in which ligand bonding is monodentate through nitrogen. Solutions of these complexes in benzene or chloroform isomerise on standing to give complexes involving 2-substituted-pyrroline derivatives as ligands. Attempts to convert this reaction into a catalytic process were unsuccessful using rhodium catalysts at 80 degrees C but catalysis was achieved using Ni(CO)(2)(PPh(3))(2) at 125 degrees C.

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页码：205 / 209

页数：5

相关论文

共 20 条

[1] THE STEREOCHEMISTRY OF ORGANOMETALLIC COMPOUNDS .60. RHODIUM-CATALYZED REACTIONS OF HYDROGEN AND CARBON-MONOXIDE WITH ALKENYLANILINES [J].

ANASTASIOU, D ;

CAMPI, EM ;

CHAOUK, H ;

FALLON, GD ;

JACKSON, WR ;

MCCUBBIN, QJ ;

TRNACEK, AE .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1994, 47 (06) :1043-1059

[2] METAL-COMPLEXES WITH ALLYLANILINES .4. SYNTHESIS AND REACTIVITY OF RHODIUM(I) COMPLEXES WITH 2-ALLYLANILINE AND N-ALLYLANILINE [J].

ARESTA, M ;

DEFAZIO, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 186 (01) :109-120

[3] ALLYLIC REARRANGEMENTS DURING THE RHODIUM-CATALYZED REACTIONS OF 2-ALLYLOXYBENZYLAMINES AND 2-(N-ALLYL-N-BENZYLAMINO)BENZYLAMINE [J].

CAMPI, EM ;

JACKSON, WR ;

MCCUBBIN, QJ ;

TRNACEK, AE .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (24) :2763-2763

[4] THE STEREOCHEMISTRY OF ORGANOMETALLIC COMPOUNDS .61. THE PREPARATION OF QUINAZOLINES AND QUINAZOLINONES INVOLVING RHODIUM-CATALYZED HYDROFORMYLATION OF ALKENYL ANILINES [J].

CAMPI, EM ;

JACKSON, WR ;

MCCUBBIN, QJ ;

TRNACEK, AE .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1994, 47 (06) :1061-1070

[5] SYNTHESIS OF SUBSTITUTED ALPHA-METHYLENE LACTAMS BY RHODIUM-CATALYZED CARBONYLATION OF ACETYLENIC AMINES [J].

CAMPI, EM ;

CHONG, JM ;

JACKSON, WR ;

VANDERSCHOOT, M .

TETRAHEDRON, 1994, 50 (08) :2533-2542

[6] RHODIUM-CATALYZED REACTIONS OF PROPARGYLAMINES WITH CO/H2 - FORMATION OF PYRROLES AND BUTENOLIDES [J].

CAMPI, EM ;

FALLON, GD ;

JACKSON, WR ;

NILSSON, Y .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1992, 45 (07) :1167-1178

[7] The stereochemistry of organometallic compounds .42. The preparation of [2,1-b]quinazolines involving rhodium-catalysed hydroformylation of 2-amino-N-alkenylbenzylamines [J].

Campi, EM ;

Habsuda, J ;

Jackson, WR ;

Jonasson, CAM ;

McCubbin, QJ .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1995, 48 (12) :2023-2033

[8]

Dannhardt G., 1990, Substituted Pyrrolizine Compounds and Their Use as Pharmaceuticals, Patent No. [EP397175, 397175]

[9] PALLADIUM-CATALYZED CYCLIZATION OF OMEGA-OLEFINIC TOSAMIDES - SYNTHESIS OF NON-AROMATIC NITROGEN-HETEROCYCLES [J].

HEGEDUS, LS ;

MCKEARIN, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (09) :2444-2451

[10] FACILE INTRAMOLECULAR DISPLACEMENT OF FLUORIDE IN REACTION OF GAMMA-FLUOROBUTYRONITRILE WITH PHENYLMAGNESIUM BROMIDE [J].

KEMPPAINEN, AE ;

THOMAS, MJ ;

WAGNER, PJ .

JOURNAL OF ORGANIC CHEMISTRY, 1976, 41 (07) :1294-1295