The coarse-graining approach to statistical mechanics: how blissful is our ignorance?

被引:26
|
作者
Ridderbos, K [1 ]
机构
[1] Univ Cambridge Darwin Coll, Cambridge CB3 9EU, England
来源
STUDIES IN HISTORY AND PHILOSOPHY OF MODERN PHYSICS | 2002年 / 33B卷 / 01期
关键词
Gibbs ensemble approach; coarse-graining; entropy; Zeroth Law of thermodynamics;
D O I
10.1016/S1355-2198(01)00037-5
中图分类号
N09 [自然科学史]; B [哲学、宗教];
学科分类号
01 ; 0101 ; 010108 ; 060207 ; 060305 ; 0712 ;
摘要
In this paper I first argue that the objection which is most commonly levelled against the coarse-graining approach -viz. that it introduces an element of subjectivity into what ought to be a purely objective formalism- is ultimately unfounded. I then proceed to argue that two different objections to the coarse-graining approach indicate that it is an inadequate approach to statistical mechanics. The first objection is based on the fact that the appeal to appearances by the coarse-graining approach fails to justify the coarse-graining strategy of ignoring the physical differences between so-called quasi-equilibrium distributions and equilibrium distributions. The second objection is centred on the notion of a coarse-grained entropy. I will argue that the required increase in the coarse-grained entropy is obtained by disregarding the dynamical constraints on the system. This undermines the very task statistical mechanics has set out to accomplish, viz. to provide a microdynamical underpinning of thermodynamics. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:65 / 77
页数:13
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