Reactivity of a terminal chromium borylene complex towards olefins: Insertion of a borylene into a C-H bond

被引：51
作者：
Braunschweig, Holger [1 ]
Dewhurst, Rian D. [1 ]
Herbst, Thomas [1 ]
Radacki, Krzysztof [1 ]
机构：
[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 32期
关键词：
boron; borylene complexes; insertion; olefins; vinylaminoboranes;
D O I：
10.1002/anie.200801579
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Borylene insertion: Irradiation of the terminal borylene complex [(OC) 5Cr=BN-(SiMe3)2] at room temperature in the presence of 3,3-dimethyl-1-butene leads to insertion of the aminoborylene moiety into the olefinic C-H bond and formation of a vinylborane complex (see structure). (Figure Presented) © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：5978 / 5980
页数：3
相关论文
共 32 条
  • [21] Vanadyl tetradentate Schiff base complexes as catalyst for C-H bond activation of olefins with tert-butylhydroperoxide:: Synthesis, characterization and structure
    Rayati, Saeed
    Torabi, Niloofar
    Ghaemi, Akbar
    Mohebbi, Sajjad
    Wojtczak, Andrzej
    Kozakiewicz, Anna
    INORGANICA CHIMICA ACTA, 2008, 361 (05) : 1239 - 1245
  • [22] C-H and C-F Bond Activation Reactions of Fluorinated Propenes at Rhodium: Distinctive Reactivity of the Refrigerant HFO-1234yf
    Talavera, Maria
    von Hahmann, Cortney N.
    Mueller, Robert
    Ahrens, Mike
    Kaupp, Martin
    Braun, Thomas
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (31) : 10688 - 10692
  • [23] A uranium(IV) imido amido triazenido complex formed via addition of a C-H bond across a U-N multiple bond
    Boreen, Michael A.
    Arnold, John
    POLYHEDRON, 2018, 155 : 149 - 152
  • [24] Intramolecular Huisgen-type cyclization of platinum-bound pyrylium ions with alkenes and subsequent insertion into a benzylic C-H bond
    Oh, Chang Ho
    Lee, Ji Ho
    Lee, Sit Jin
    Kim, Jae Il
    Hong, Chang Seop
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (39) : 7505 - 7507
  • [25] Formation of a Dinuclear Rh(I)-/Rh(I)+ Complex Exhibiting MMCT Absorption from Dianionic Diborane(4) through C-H Bond Cleavage
    Akiyama, Seiji
    Yamashita, Makoto
    CHEMISTRY LETTERS, 2020, 49 (06) : 721 - 723
  • [26] Cooperative C-H Bond Activation by a Low-Spin d6 Iron-Aluminum Complex
    Gorgas, Nikolaus
    White, Andrew J. P.
    Crimmin, Mark R.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2022, 144 (19) : 8770 - 8777
  • [27] Palladium-Catalyzed Alkenylation of 1,2,3-Trizoles with Terminal Conjugated Alkenes by Direct C-H Bond Functionalization
    Jiang, Huanfeng
    Feng, Zhenning
    Wang, Azhong
    Liu, Xiaohang
    Chen, Zhengwang
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2010, 2010 (07) : 1227 - 1230
  • [28] Direct Allylic C-H Bond Activation To Synthesize [Pd(η3-cin)(IPr)CI] Complex: Application in the Allylation of Oxindoles
    Hu, Rong-Bin
    Wang, Chun-Hai
    Ren, Wei
    Liu, Zhong
    Yang, Shang-Dong
    ACS CATALYSIS, 2017, 7 (11): : 7400 - 7404
  • [29] Alkyne Insertion into the M-P and M-H Bonds (M = Pd, Ni, Pt, and Rh): A Theoretical Mechanistic Study of the C-P and C-H Bond-Formation Steps
    Ananikov, Valentine P.
    Beletskaya, Irina P.
    CHEMISTRY-AN ASIAN JOURNAL, 2011, 6 (06) : 1423 - 1430
  • [30] Isomerization of Internal Alkynes to Iridium(III) Allene Complexes via C-H Bond Activation: Expanded Substrate Scope, and Progress towards a Catalytic Methodology
    Phadke, Neha
    Findlater, Michael
    MOLECULES, 2015, 20 (11): : 20195 - 20205
1234