Reactivity of a terminal chromium borylene complex towards olefins: Insertion of a borylene into a C-H bond

被引：51
|
作者：
Braunschweig, Holger [1 ]
Dewhurst, Rian D. [1 ]
Herbst, Thomas [1 ]
Radacki, Krzysztof [1 ]
机构：
[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 32期
关键词：
boron; borylene complexes; insertion; olefins; vinylaminoboranes;
D O I：
10.1002/anie.200801579
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Borylene insertion: Irradiation of the terminal borylene complex [(OC) 5Cr=BN-(SiMe3)2] at room temperature in the presence of 3,3-dimethyl-1-butene leads to insertion of the aminoborylene moiety into the olefinic C-H bond and formation of a vinylborane complex (see structure). (Figure Presented) © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：5978 / 5980
页数：3
相关论文
共 32 条
  • [1] Unprecedented Borylene Insertion into a C-N Bond
    Ghadwal, Rajendra S.
    Schuermann, Christian J.
    Engelhardt, Felix
    Steinmetzger, Christian
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2014, (29) : 4921 - 4926
  • [2] Transition-metal-carbene-like intermolecular insertion of a borylene into C-H bonds
    Liu, Siyuan
    Legare, Marc-Andre
    Hofmann, Alexander
    Dellermann, Theresa
    Braunschweig, Holger
    CHEMICAL COMMUNICATIONS, 2020, 56 (53) : 7277 - 7280
  • [3] Reactivity of Transition-Metal Borylene Complexes: Recent Advances in B-C and B-B Bond Formation via Borylene Ligand Coupling
    Braunschweig, Holger
    Shang, Rong
    INORGANIC CHEMISTRY, 2015, 54 (07) : 3099 - 3106
  • [4] Reactivity of the bridged borylene complex [μ-BCl{η5-C5H4Me)Mn(CO)2}2]
    Braunschweig, H
    Colling, M
    Hu, CH
    Radacki, K
    INORGANICA CHIMICA ACTA, 2004, 357 (06) : 1822 - 1828
  • [5] Reactivity of Cationic Terminal Borylene Complexes: Novel Mechanisms for Insertion and Metathesis Chemistry Involving Strongly Lewis Acidic Ligand Systems
    De, Susmita
    Pierce, Glesni A.
    Vidovic, Dragoslav
    Kays, Deborah L.
    Coombs, Natalie D.
    Jemmis, Eluvathingal D.
    Aldridge, Simon
    ORGANOMETALLICS, 2009, 28 (10) : 2961 - 2975
  • [6] Reactivity of Terminal Iron Borylenes and Bis(borylenes) with Carbodiimides: Cycloaddition, Metathesis, Insertion and C-H Activation Pathways
    Matler, Alexander
    Arrowsmith, Merle
    Schorr, Fabian
    Hermann, Alexander
    Hofmann, Alexander
    Lenczyk, Carsten
    Braunschweig, Holger
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2021, 2021 (45) : 4619 - 4631
  • [7] [(η5-C5H5)(OC3V=B=N(SiMe3)2:: a half-sandwich complex with a terminal borylene ligand
    Braunschweig, H
    Colling, M
    Hu, CH
    Radacki, K
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (02) : 205 - +
  • [8] Reactivity of Diruthenium Bisborylene Complexes: Formation of B-C and B-H Bonds via Borylene Ligand Coupling
    Wei, Yongliang
    Yang, Xiaowen
    Liu, Min
    Wang, Xue
    Li, Yang
    Wang, Tongdao
    INORGANIC CHEMISTRY, 2024, 63 (44) : 20945 - 20950
  • [9] MOLECULAR STRUCTURE, NATURAL BOND ORBITAL, SUBSTITUENT EFFECT AND CHEMICAL REACTIVITY ANALYSIS OF TERMINAL BORYLENE RUTHENIUM COMPLEXES: Ru(PH3)2HCl(BC6H4X)
    Ghiasi, Reza
    Mehrabani, Mahbobeh Mahbobi
    JOURNAL OF THEORETICAL & COMPUTATIONAL CHEMISTRY, 2013, 12 (07)
  • [10] Cobalt-Catalyzed Chemoselective Insertion of Alkene into the Ortho C-H Bond of Benzamide
    Ilies, Laurean
    Chen, Quan
    Zeng, Xiaoming
    Nakamura, Eiichi
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (14) : 5221 - 5223
1234