2D siloxene supported NiO/Co3O4 electrocatalyst for the stable and efficient hydrogen evolution reaction

被引:5
作者
Huynh, Ngoc-Diem [1 ]
Jana, Jayasmita [1 ]
Nivetha, Ravi [1 ]
Van Phuc, Tran [1 ]
Chung, Jin Suk [1 ]
Hur, Seung Hyun [1 ]
机构
[1] Univ Ulsan, Sch Chem Engn, Daehak ro 93, Ulsan 44610, South Korea
关键词
Siloxene; HER; Water splitting; Metal oxides; X-RAY PHOTOELECTRON; HIGH-PERFORMANCE; OXYGEN; NI; CO; NANOSTRUCTURES; NANOPARTICLES; NICKEL; COBALT; HETEROSTRUCTURES;
D O I
10.1016/j.cap.2022.10.001
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The activity of NiO/Co3O4 for the hydrogen evolution reaction (HER) during water splitting was increased by depositing these metal oxides on siloxene multi-sheets. The improvement in active sites due to siloxene was used to increase the catalytic activity. The hierarchical structure of the composite with the synergistic effect of metal oxides helped enhance the catalytic activity to show a low overpotential of 110 mV at 10 mA/cm2 in 1 M KOH and stability at 10 mA/cm2 over 20 h without an obvious change in voltage. The as-prepared catalyst can be a promising electrocatalyst for the HER owing to the low cost of transition metal oxides, the abundance of silicon on Earth, and the simplicity of the synthesis process.
引用
收藏
页码:102 / 109
页数:8
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