Amphiphiles Based on D-Glucose: Efficient Low Molecular Weight Gelators

被引:30
作者
Nandi, Sukhendu [1 ]
Altenbach, Hans-Josef [1 ]
Jakob, Bernd [1 ]
Lange, Karsten [1 ]
Ihizane, Rachid [1 ]
Schneider, Manfred P. [1 ]
Guen, Uemit [1 ]
Mayer, Andre [2 ]
机构
[1] Berg Univ Wuppertal, FB C Organ Chem, D-42119 Wuppertal, Germany
[2] Berg Univ Wuppertal, FBC Mikrostrukturtech, D-42119 Wuppertal, Germany
关键词
GEL; ORGANOGELS; GELATION; WATER; HYDROGELATORS; DERIVATIVES; BEHAVIOR; SULFATE; RECOGNITION; SYSTEM;
D O I
10.1021/ol300555a
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A series of novel amphiphiles were synthesized based entirely on renewable resources. Besides their efficacy as supramolecular gelators in a wide variety of organic solvents and also water, their surface properties as surfactants and emulsifiers have been determined. A methodical study revealed that the length of the hydrocarbon chains has a dramatic and decisive influence on the thermal stabilities of the obtained hydrogels.
引用
收藏
页码:3826 / 3829
页数:4
相关论文
共 64 条
[1]   Cholesterol-aided supramolecular control over chromophore packing: Twisted and coiled helices with distinct optical, chiroptical, and morphological features [J].
Ajayaghosh, A ;
Vijayakumar, C ;
Varghese, R ;
George, SJ .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (03) :456-460
[2]   π-organogels of self-assembled p-phenylenevinylenes:: Soft materials with distinct size, shape, and functions [J].
Ajayaghosh, Ayyappanpillai ;
Praveen, Vakayil K. .
ACCOUNTS OF CHEMICAL RESEARCH, 2007, 40 (08) :644-656
[3]  
ALTENBACH HJ, 2010, Patent No. 102009015461
[4]   Structure calculation of an elastic hydrogel from sonication of rigid small molecule components [J].
Anderson, Kirsty M. ;
Day, Graeme M. ;
Paterson, Martin J. ;
Byrne, Peter ;
Clarke, Nigel ;
Steed, Jonathan W. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (06) :1058-1062
[5]   Excited State Processes in Linear π-System-Based Organogels [J].
Babu, Sukumaran S. ;
Kartha, Kalathil K. ;
Ajayaghosh, Ayyappanpillai .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2010, 1 (23) :3413-3424
[6]   Self-Assembled Gelators for Organic Electronics [J].
Babu, Sukumaran Santhosh ;
Prasanthkumar, Seelam ;
Ajayaghosh, Ayyappanpillai .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (08) :1766-1776
[7]   Triclosan inhibits sodium lauryl sulphate-induced changes in expression of cytokeratin genes in hamster cheek pouch epithelium [J].
Baert, JH ;
Veys, RJ .
JOURNAL OF ORAL PATHOLOGY & MEDICINE, 1997, 26 (04) :181-186
[8]   Recent developments of molecular chemistry for sol-gel processes [J].
Corriu, RJP ;
Leclercq, D .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (13-14) :1420-1436
[9]   Vesicle Formation and Microphase Behavior of Amphiphilic ABC Triblock Copolymers in Selective Solvents: A Monte Carlo Study [J].
Cui, Jie ;
Jiang, Wei .
LANGMUIR, 2010, 26 (16) :13672-13676
[10]   Sulfate recognition by persistent crystalline capsules with rigidified hydrogen-bonding cavities [J].
Custelcean, Radu ;
Remy, Priscilla ;
Bonnesen, Peter V. ;
Jiang, De-En ;
Moyer, Bruce A. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (10) :1866-1870