PO43--Mediated Polyoxometalate Supercluster Assembly

被引：131
作者：
Fang, Xikui [1 ]
Koegerler, Paul [1 ]
机构：
[1] Iowa State Univ, Ames Lab, Ames, IA 50011 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 42期
关键词：
cerium; manganese; phosphate; polyoxometalates; template synthesis;
D O I：
10.1002/anie.200802491
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Small anion, big task: The assembly of a ten-component, heterochiral polyoxometalate aggregate, driven by the templating effect of a single phosphate anion, proceeds through a coordination-number-controlled formation route from three dimeric Dawson anion based magnetic building blocks. (Figure Presented). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：8123 / 8126
页数：4
相关论文
共 36 条
[21]  
MIALANE P, 2003, ANGEW CHEM, V115, P3647
[22]   SUPRAMOLECULAR INORGANIC-CHEMISTRY - SMALL GUESTS IN SMALL AND LARGE HOSTS [J].
MULLER, A ;
REUTER, H ;
DILLINGER, S .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (21) :2328-2361
[23]   Template-mediated self assembly of six- and eight-membered iron coronates [J].
Saalfrank, RW ;
Bernt, I ;
Uller, E ;
Hampel, F .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (22) :2482-2485
[24]  
SAALFRANK RW, 1997, ANGEW CHEM, V109, P2596
[25]   Supramolecular chirality in coordination chemistry [J].
Seeber, Georg ;
Tiedemann, Bryan E. F. ;
Raymond, Kenneth N. .
SUPRAMOLECULAR CHIRALITY, 2006, 265 :147-183
[26]  
Tasiopoulos A.J., 2004, ANGEW CHEM, V116, P349
[27]   Mixed transition-metal-lanthanide complexes at higher oxidation states:: Heteronuclear CeIV-MnIV clusters [J].
Tasiopoulos, AJ ;
O'Brien, TA ;
Abboud, KA ;
Christou, G .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (03) :345-349
[28]   Template synthesis and single-molecule magnetism properties of a complex with spin S=16 and a [Mn8O8]8+ saddle-like core [J].
Tasiopoulos, AJ ;
Wernsdorfer, W ;
Moulton, B ;
Zaworotko, MJ ;
Christou, G .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (50) :15274-15275
[29]   Mixed transition metal-lanthanide complexes at high oxidation states:: Heteronuclear CeIVMnIV clusters [J].
Tasiopoulost, Anastasios J. ;
Milligan, Paul L., Jr. ;
Abboud, Khalil A. ;
O'Brien, Ted A. ;
Christou, George .
INORGANIC CHEMISTRY, 2007, 46 (23) :9678-9691
[30]   Anion-templated synthesis [J].
Vilar, R .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (13) :1460-1477
1234