PO43--Mediated Polyoxometalate Supercluster Assembly

被引：131
作者：
Fang, Xikui [1 ]
Koegerler, Paul [1 ]
机构：
[1] Iowa State Univ, Ames Lab, Ames, IA 50011 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 42期
关键词：
cerium; manganese; phosphate; polyoxometalates; template synthesis;
D O I：
10.1002/anie.200802491
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Small anion, big task: The assembly of a ten-component, heterochiral polyoxometalate aggregate, driven by the templating effect of a single phosphate anion, proceeds through a coordination-number-controlled formation route from three dimeric Dawson anion based magnetic building blocks. (Figure Presented). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：8123 / 8126
页数：4
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