Synthesis of Lower Olefins from Synthesis Gas over Active Carbon-Supported Iron Catalyst

被引：15

作者：

Asami, Kenji ^{[1
]}

Komiyama, Kazuki ^{[1
]}

Yoshida, Kohei ^{[1
]}

Miyahara, Hiroki ^{[1
]}

机构：

[1] Univ Kitakyushu, Kitakyushu, Fukuoka 8080135, Japan

来源：

CATALYSIS TODAY | 2018年 / 303卷

关键词：

Lower olefin; Iron catalyst; Active carbon; Synthesis gas; Fischer-Tropsch synthesis; FISCHER-TROPSCH SYNTHESIS; LIGHT ALKENES;

D O I：

10.1016/j.cattod.2017.09.010

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Synthesis of C-2-C-6 lower olefins from synthesis gas was investigated through Fischer-Tropsch synthesis (FTS) reaction over active carbon-supported iron catalyst with a small amount of Cu (Fe-Cu/AC) catalysts using a fixed bed reactor at 300 degrees C at 2.1 MPa. Mn promoted catalyst (Fe-Cu-Mn/AC) gave high yield and selectivity to the lower olefins. Added Mn species seemed likely to locate uniformly on the AC surface to form complex oxide with iron oxide. A high yield of ca. 40% is obtainable at high H-2/CO ratio of 4. The catalyst showed stable activity and selectivity for 100 h. CO2 addition in the feed gas enhances the yield further by suppressing the water gas shift reaction.

引用

页码：117 / 122

页数：6