Electrical characterization and conduction mechanism of impurity-doped BaSi2 films grown on Si(111) by molecular beam epitaxy

被引:47
作者
Khan, M. Ajmal [1 ]
Saito, T. [1 ]
Nakamura, K. [1 ]
Baba, M. [1 ]
Du, W. [1 ]
Toh, K. [1 ]
Toko, K. [1 ]
Suemasu, T. [1 ,2 ]
机构
[1] Univ Tsukuba, Inst Appl Phys, Tsukuba, Ibaraki 3058573, Japan
[2] Japan Sci & Technol Agcy, CREST, Chiyoda Ku, Tokyo 1020075, Japan
关键词
Barium silicide; Molecular beam epitaxy; Impurity doping; Solar cells; DEPTH PROFILES; COULOMB GAP; THIN-FILMS; CU; SUBSTRATE; AL;
D O I
10.1016/j.tsf.2012.09.005
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The carrier concentrations and mobilities of impurity (Sb, In, Ga, Al, Ag, and Cu)-doped BaSi2 films grown by molecular beam epitaxy on highly resistive n-or p-Si(111) substrates were measured at room temperature using the van der Pauw technique. Sb-, Ga- and Cu-doped BaSi2 exhibited n-type conductivity, while InAl- and Ag-doped BaSi2 exhibited p-type conductivity. The temperature dependence of resistivity indicated that the carrier transport in Ga-, Al-, Ag-, and Cu-doped BaSi2 is well explained by both Shklovskii-Efros-type and Mott-type variable range hopping conduction. (C) 2012 Elsevier B. V. All rights reserved.
引用
收藏
页码:95 / 99
页数:5
相关论文
共 26 条
[1]  
[Anonymous], PHYS STATUS SOLIDI B
[2]   Hopping conductivity in Mn-doped β-FeSi2 single crystals [J].
Arushanov, E. ;
Lisunov, K. G. ;
Vinzelberg, H. ;
Behr, G. ;
Schumann, J. ;
Schmidt, O. G. .
JOURNAL OF APPLIED PHYSICS, 2008, 104 (05)
[3]   COULOMB GAP IN DISORDERED SYSTEMS [J].
EFROS, AL .
JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1976, 9 (11) :2021-2030
[4]   COULOMB GAP AND LOW-TEMPERATURE CONDUCTIVITY OF DISORDERED SYSTEMS [J].
EFROS, AL ;
SHKLOVSKII, BI .
JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1975, 8 (04) :L49-L51
[5]   CRYSTAL-STRUCTURE OF BARIUM DISILICIDE AT HIGH-PRESSURES [J].
EVERS, J ;
OEHLINGER, G ;
WEISS, A .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1977, 16 (09) :659-660
[7]   ELECTRICAL-RESISTIVITY OF METASTABLE PHASES OF BASI2 SYNTHESIZED UNDER HIGH-PRESSURE AND HIGH-TEMPERATURE [J].
IMAI, M ;
HIRANO, T .
JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 224 (01) :111-116
[8]   Energetic evaluation of possible insertion sites of Cu into BaSi2 using first principle calculations [J].
Imai, Y. ;
Watanabe, A. .
INTERMETALLICS, 2011, 19 (08) :1102-1106
[9]   Consideration of the band-gap tunability of BaSi2 by alloying with Ca or Sr based on the electronic structure calculations [J].
Imai, Yoji ;
Watanabe, Akio .
THIN SOLID FILMS, 2007, 515 (22) :8219-8225
[10]   Energetic and the electronic structural consideration of the 13th Group element (Ga and In) impurity doping. to control the conductivity of BaSi2 [J].
Imai, Yoji ;
Watanabe, Akio .
INTERMETALLICS, 2007, 15 (10) :1291-1296