Intermolecular chemo- and regioselective aromatic C-H amination of alkoxyarenes promoted by rhodium nitrenoids

被引：18
|
作者：
Arai, Kenta [1 ]
Ueda, Yoshihiro [1 ]
Morisaki, Kazuhiro [1 ]
Furuta, Takumi [1 ]
Sasamori, Takahiro [2 ]
Tokitoh, Norihiro [1 ]
Kawabata, Takeo [1 ]
机构：
[1] Kyoto Univ, Inst Chem Res, Uji, Kyoto 6110011, Japan
[2] Nagoya City Univ, Grad Sch Nat Sci, Mizuho Ku, Yamanohata 1,Mizuho Cho, Nagoya, Aichi 4678501, Japan
来源：
CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 18期
关键词：
RH-CATALYZED AMINATION; FUNCTIONAL MOLECULES; PHOTOREDOX CATALYSIS; ORIENTED AROMATICS; BONDS; IMIDATION; INSERTIONS; OXIDATION; AMINES; OXAZOLIDINONES;
D O I：
10.1039/c7cc09952e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Intermolecular aromatic C(sp(2))-H amination promoted by neutral rhodium nitrenoids has been developed. The reactions proceeded with various oxygen-substituted arenes (1.5 equiv.) in a chemo- and regioselective manner. The aromatic C(sp(2))-H amination took place at the para position of the oxygen substituent in the presence of benzylic C(sp(3))-H bonds and/or C(sp(3))-H bonds to ethereal oxygen.
引用
收藏
页码：2264 / 2267
页数：4
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