Surface analysis and electrochemical behavior of Ti-20Zr alloy in simulated physiological fluids

被引：15

作者：

Moreno, Jose Maria Calderon ^{[1
]}

Vasilescu, Ecaterina ^{[1
]}

Drob, Paula ^{[1
]}

Osiceanu, Petre ^{[1
]}

Vasilescu, Cora ^{[1
]}

Drob, Silviu Iulian ^{[1
]}

Popa, Monica ^{[1
]}

机构：

[1] Romanian Acad, Inst Phys Chem Ilie Murgulescu, Bucharest 060021, Romania

来源：

MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS | 2013年 / 178卷 / 18期

关键词：

Long-term passive film; Microstructure; EIS; XPS; SEM; Raman micro-spectroscopy; CORROSION BEHAVIOR; MECHANICAL-PROPERTIES; IMPEDANCE SPECTROSCOPY; TI-6AL-7NB ALLOY; ANODIC OXIDES; BODY-FLUID; TITANIUM; ZIRCONIUM; TI; RESISTANCE;

D O I：

10.1016/j.mseb.2013.07.006

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

An advanced Ti-20Zr alloy was obtained by double vacuum melting in a semi-levitation furnace with cold crucible. The alloy shows fully lamellar alpha + beta microstructure. Cyclic potentiodynamic polarization curves revealed that the alloy passivated easier, more rapid than Ti, having a more stable passive film in Ringer solutions of different pH values, simulating severe functional conditions of an implant. In neutral and alkaline Ringer solutions, the alloy passive film improved its properties in time (1500h) by the deposition of protective hydroxyapatite, as was demonstrated by XPS, SEM, EDX, Raman and FT-IR measurements. Alloy presented lower corrosion rates and higher polarization resistances (from linear polarization measurements) than those of Ti (tens of times) proving a more resistant passive film. Alloy open circuit potentials had more electropositive values in comparison with Ti and tended to nobler values in time, which denote better passive state and its enhancement in time, due to the new depositions from the physiological solutions. Nyquist and Bode spectra depicted a more protective passive film on the alloy surface than on Ti surface. The passive film is formed by two layers: an inner barrier layer and an outer porous layer. An electric equivalent circuit with two time constants was modeled. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：1195 / 1204

页数：10

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