Tubular Arrangement of 1,3-Alternate Calix[4]arene with Bipyridines: A Platform for [2+2] Photocyclization

被引：7
|
作者：
Lee, Eunji
Ju, Huiyeong
Lee, Shim Sung [1 ]
Park, Ki-Min
机构：
[1] Gyeongsang Natl Univ, Dept Chem, Jinju 660701, South Korea
来源：
CRYSTAL GROWTH & DESIGN | 2013年 / 13卷 / 03期
关键词：
SOLID-STATE; CO-CRYSTALS; PHARMACEUTICAL COCRYSTALS; SUPRAMOLECULAR SYNTHONS; COORDINATION POLYMERS; ACIDS; 4,4'-BIPYRIDINE; REACTIVITY; PYRIDINE; 2D;
D O I：
10.1021/cg301854f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
By using a 1,3-alternate conformation of calix[4]arene tetrabenzoic acid (H4CTB), a pair of 4,4'-bipyridine has been aligned forming a cocrystallized one-dimensional tubular product 1. Inspired by this result, the 1,3-alternate H4CTB has been utilized as "clips" to anchor the C=C bond pairs of 4,4'-bipyridylethene to give an isotypical H-bonded tubular product 2 which undergoes the solid-state photodimerization.
引用
收藏
页码：992 / 995
页数：4
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