2-(1-Methylethoxy)-5-nitrophenyl N-methylcarbamate

被引:1
作者
Sang, Guang-Ming [2 ]
Luo, Shi-Neng [1 ]
Lin, Jian-Guo [1 ]
Yang, Hai-Lin [3 ]
Xia, Yong-Mei [2 ]
机构
[1] Jiangsu Inst Nucl Med, Minist Hlth, Key Lab Nucl Med, Wuxi 214063, Peoples R China
[2] Jiangnan Univ, Sch Chem & Mat Engn, Wuxi 214122, Peoples R China
[3] Jiangnan Univ, Key Lab Ind Biotechnol, Wuxi 214122, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词
PROPOXUR;
D O I
10.1107/S1600536808040622
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C11H14N2O5, the nitro group is approximately coplanar with the benzene ring, making a dihedral angle of 4.26 (17)degrees. The dihedral angle between the methylcarbamate group and the benzene ring is 72.47 (6)degrees. There is a strong intermolecular N-H center dot center dot center dot O hydrogen bond between the N and O atoms from adjacent methylcarbamate groups, forming a one-dimensional network along the a axis.
引用
收藏
页码:O47 / U1674
页数:9
相关论文
共 7 条
  • [1] The relative directive powers of groups of the forms RO and RR'N in aromatic substitution. Part IV. A discussion of the observations recorded in Parts I, II, and III.
    Allan, J
    Oxford, AE
    Robinson, R
    Smith, JC
    [J]. JOURNAL OF THE CHEMICAL SOCIETY, 1926, : 401 - 411
  • [2] [Anonymous], 2001, SMART SAINT
  • [3] CZUGLER M, 1975, CRYST STRUCT COMMUN, V4, P531
  • [4] Production of monoclonal antibodies to the N-methylcarbamate pesticide propoxur
    Moreno, MJ
    Abad, A
    Montoya, A
    [J]. JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2001, 49 (01) : 72 - 78
  • [5] A short history of SHELX
    Sheldrick, George M.
    [J]. ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 : 112 - 122
  • [6] Genotoxicity of propoxur and its N-nitroso derivative in mammalian cells
    Wang, TC
    Chiou, JM
    Chang, YL
    Hu, MC
    [J]. CARCINOGENESIS, 1998, 19 (04) : 623 - 629
  • [7] 2,3-dihydro-2,2-dimethylbenzofuran-7-yl-N-methylcarbamate
    Xu, LZ
    Yu, GP
    Yang, SH
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O1924 - O1926