Isobaric vapor-liquid equilibria of chloroform plus ethanol and chloroform plus ethanol plus calcium chloride at 94.0 kPa

被引:10
作者
Darwish, NA
AlAnber, ZA
机构
[1] Jordan Univ of Science and, Technology, Irbid, Jordan
关键词
experimental; data; vapor-liquid equilibria; excess (properties); model; calcium chloride;
D O I
10.1016/S0378-3812(96)03203-7
中图分类号
O414.1 [热力学];
学科分类号
摘要
Vapor-liquid equilibrium data of chloroform + ethanol and chloroform + ethanol + CaCl2 (at saturation) were measured at a pressure of 94.0 kPa, using a modified Malanowski equilibrium still. The salt investigated in this work, i.e. CaCl2, exhibits a slight salting-out effect on chloroform. The experimental results of the salt-free binary were compared with those predicted by ASOG, original UNIFAC, and modified UNIFAC models which predicted the bubble point temperatures with a root-mean-square-deviation (RMSD) of: 0.40, 0.55, and 1.48 K, respectively. RMSD values of the vapor-phase composition given by these models were: 0.020, 0.019 and 0.039 mole fraction, respectively. On the other hand, the experimental data of the salt-containing system were compared with those predicted by Wilson-Tan and NRTL-Tan models for the effect of the electrolyte on the phase behavior of the system under study which has an azeotrope around x(1) = 0.93. Both models showed similar capability in predicting the bubble-point temperatures and vapor-phase compositions: temperatures were predicted by both models with an RMSD of about 0.4 K whereas the RMSD values of the vapor-phase mole fractions, predicted by these models, were 0.026 and 0.022, respectively. (C) 1997 Elsevier Science B.V.
引用
收藏
页码:259 / 267
页数:9
相关论文
共 19 条
[1]  
AMIT S, 1991, THESIS OKLAHOMA STAT
[2]  
Cheng-Long L., 1993, FLUID PHUSE EQUILIB, V90, P57
[3]  
Ciparis J.N., 1966, DATA SALT EFFECT VAP
[4]  
DARWISH NA, IN PRESS FLUID PHASE
[5]  
Fredenslund A., 1977, Vapor-liquid equilibria using UNIFAC: A Group-Contribution method
[6]   SALT EFFECT IN DISTILLATION - A LITERATURE REVIEW [J].
FURTER, WF ;
COOK, RA .
INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 1967, 10 (01) :23-&
[7]   SALT EFFECT IN DISTILLATION - LITERATURE-REVIEW .2. [J].
FURTER, WF .
CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1977, 55 (03) :229-239
[8]   A MODIFIED UNIFAC MODEL .2. PRESENT PARAMETER MATRIX AND RESULTS FOR DIFFERENT THERMODYNAMIC PROPERTIES [J].
GMEHLING, J ;
LI, JD ;
SCHILLER, M .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1993, 32 (01) :178-193
[9]   SALT EFFECT ON VAPOR-LIQUID-EQUILIBRIA - A REVIEW OF CORRELATIONS AND PREDICTIVE MODELS [J].
KUMAR, A .
SEPARATION SCIENCE AND TECHNOLOGY, 1993, 28 (10) :1799-1818
[10]  
MALANOWSKI S, 1992, MODELING PHASE EQUIL