Novel partially bio-based fluorinated polyimides from dimer fatty diamine for UV-cured coating

被引：16

作者：

Liu, Jingcheng ^{[1
]}

Wang, Kuan ^{[1
]}

Xie, Yazhen ^{[1
]}

Gao, Fei ^{[1
]}

Zeng, Qingtao ^{[1
]}

Yuan, Yan ^{[1
]}

Liu, Ren ^{[1
]}

Liu, Xiaoya ^{[1
]}

机构：

[1] Jiangnan Univ, Sch Chem & Mat Engn, Minist Educ, Key Lab Food Colloids & Biotechnol, Wuxi 214122, Peoples R China

来源：

JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH | 2017年 / 14卷 / 06期

基金：

中国国家自然科学基金;

关键词：

Fluorinated polyimides; Bio-based; UV-cured coating; SHAPE-MEMORY POLYMERS; HIGH-PERFORMANCE; OPTICAL TRANSPARENCY; BIOBASED POLYIMIDES; SOYBEAN OIL; FILMS; OLIGOMERS; ETHER; ACID;

D O I：

10.1007/s11998-017-9931-8

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A series of novel partially bio-based fluorinated polyimides with double-bond end groups (BGPIs) from 4,4'-(hexafluoroisopropylidene) diphthalic anhydride, 4,4'-(hexafluoroisopropylidene) dianiline, Priamine 1074, 4-aminobenzoic acid, and glycidyl methacrylate were synthesized via a copolycondensation method in m-cresol. The chemical structure and performances of BGPIs were fully characterized by Fourier transform infrared spectroscopy, proton nuclear magnetic resonance, gel permeation chromatography, solubility test, X-ray diffraction, and differential scanning calorimetry. It was determined that the prepared BGPIs were in the amorphous phase and readily soluble in conventional aprotic polar solvents. Additionally, the properties of as-prepared UV-cured coatings based on BGPIs were also evaluated by real-time Fourier transform infrared, thermogravimetric analysis, UV-Vis spectroscopy, and so on. Results revealed that all coatings exhibited satisfactory curing, higher adhesion, lower water uptakes, outstanding optical transparency, and fairly favorable thermal stability under a high content of biomass up to 48.9%. Therefore, these bio-based polymers could be considered as a potential sustainable candidate for high-temperature UV-curable coatings in the microelectronic field.

引用

页码：1325 / 1334

页数：10

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