The field trials of a prompt gamma neutron activation (PGNAA) spectrometric logging method and instrumentation (SIROLOG) for copper grade estimation in production holes of a porphyry type copper ore mine, Chuquicamata. in Chile, are described. Examples of data analysis, calibration procedures and copper grade profiles are provided. The field tests have proved the suitability of the PGNAA logging system for in situ quality control of copper ore. (C) 2004 Elsevier Ltd. All rights reserved.