Basic ionic liquid as catalysis and reaction medium:: A novel and green protocol for the markovnikov addition of N-heterocycles to vinyl esters, using a task-specific ionic liquid, [bmIm]OH

被引：125

作者：

Xu, JM ^{[1
]}

Liu, BK ^{[1
]}

Wu, WB ^{[1
]}

Qian, C ^{[1
]}

Wu, Q ^{[1
]}

Lin, XF ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2006年 / 71卷 / 10期

关键词：

D O I：

10.1021/jo0600914

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A basic ionic liquid, 1-methyl-3-butylimidazolium hydroxide ([bmIm]OH), has been introduced as a catalyst and reaction medium for the Markovnikov addition of N-heterocycles to vinyl esters under mild conditions. The evidence for the role of this basic ionic liquid [bmIm]OH in promoting the Markovnikov addition has been given. On the basis of the evidence, a mechanism was postulated.

引用

页码：3991 / 3993

页数：3

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