Diethyl chlorophosphate: A mild and versatile reagent for the one-pot preparation of isothiocyanates from amines

被引：6

作者：

Kaboudin, Babak ^{[1
]}

Jafari, Ehsan ^{[1
]}

机构：

[1] IASBS, Dept Chem, Gava Zang 451951159, Zanjan, Iran

来源：

SYNTHESIS-STUTTGART | 2008年 / 17期

关键词：

isothiocyanates; amines; diethyl chlorophosphate; phosphoroamidates;

D O I：

10.1055/s-2008-1067202

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple, efficient, and new method has been developed for the synthesis of isothiocyanates from amines. The reaction of a variety of aromatic and aliphatic amines with carbon disulfide in the presence of diethyl chlorophosphate as an efficient reagent proceeded effectively to afford the corresponding isothiocyanates in moderate yields. This method is easy, rapid, and moderate-yielding for the synthesis of isothiocyanates from amines.

引用

页码：2683 / 2685

页数：3

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