Ferrocenyl-QUINAP:: a planar chiral P,N-ligand for palladium-catalyzed allylic substitution reactions

被引：60

作者：

Kloetzing, RJ ^{[1
]}

Knochel, P ^{[1
]}

机构：

[1] Univ Munich, Dept Chem & Biochem, D-81377 Munich, Germany

来源：

TETRAHEDRON-ASYMMETRY | 2006年 / 17卷 / 01期

关键词：

D O I：

10.1016/j.tetasy.2005.12.001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new planar chiral P,N-ligands 1a and 1b were prepared via a straightforward enantioselective synthesis using a Negishi cross-coupling and a sulfoxide/lithium exchange. Ligand la was successfully applied to Pd-catalyzed allylic alkylation (86% ee) and amination (83% ee) reactions. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：116 / 123

页数：8

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