Ni(cod)2/PCy3-Catalyzed Cross-Coupling Reactions of Dihaloarenes with Arylboronic Acids

被引：4

作者：

Dong, Cheng-Guo

Hu, Qiao-Sheng ^{[1
]}

机构：

[1] CUNY Coll Staten Isl, Dept Chem, Staten Isl, NY 10314 USA

来源：

SYNLETT | 2012年 / 14期

关键词：

cross-coupling; nickel; dihaloarenes; arylboronic acids; preferential oxidative addition; CATALYST-TRANSFER POLYCONDENSATION; CHAIN-GROWTH POLYMERIZATIONS; SUZUKI POLYCONDENSATION; PRECISION SYNTHESIS; POLY(P-PHENYLENE); POLYFLUORENE; COPOLYMERS; FLUORENE; SINGLE; STEP;

D O I：

10.1055/s-0031-1290455

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Ni(0)-catalyzed cross-coupling reactions of dihaloarenes with one equivalent of arylboronic acids is described. The Ni(cod)(2)/PCy3 was identified as the best catalyst system to achieve a double cross-coupling reaction, likely via an efficient preferential oxidative addition.

引用

收藏

页码：2121 / 2125

页数：5

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