4,10-dinitro-2,6,8,12-tetraoxa-4, 10-diazaisowurtzitane(TEX)

被引：0

作者：

Bahulayan, D ^{[1
]}

Ghee, AH ^{[1
]}

机构：

[1] Nanyang Technol Univ, Energent Mat Res Ctr, Sch Mat Sci & Engn, Singapore 639798, Singapore

来源：

THEORY AND PRACTICE OF ENERGETIC MATERIALS, VOL 6 | 2005年

关键词：

4,10-dinitro-2,6,8,12-tetraoxa-4; 10-diazaisowurtzitane(TEX); nitration; 1,4-diformyl-2,3,5,6-tetrahydroxypiperazine; Glyoxal; montmorillonite K10 clay; iron(III) nitrate; clayfen; menke condition;

D O I：

暂无

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

An efficient green route for the synthesis of 4, 10-Dinitro-2, 6, 8, 12-tetraoxa4, 10-diazaisowurtzitane (TEX) (3) is developed by the nitration of a mixture of 1, 4-diformyl-2, 3, 5, 6- tetrahydroxypiperazine (1) and glyoxal solution in water (2) using montmorillonite K10 clay -supported iron (III) nitrate (Clayfen) as nitrating agent at room temperature in the presence of acetic anhydride under Menke condition.

引用

页码：11 / 14

页数：4

共 27 条

[11] BASE-CATALYSED REACTIONS OF GLYOXAL .I. 1,4-DIFORMYL- AND 1,4-BISMETHYLSULPHONYL- DERIVATIVES OF 2,3,5,6-TETRAHYDROXYPIPERAZINES [J].

CURRIE, AC ;

DINWOODIE, AH ;

FORT, G ;

THOMPSON, JM .

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1967, (06) :491-+

[12] HEIGHTENED SELECTIVITY IN AROMATIC NITRATIONS AND CHLORINATIONS BY THE USE OF SOLID SUPPORTS AND CATALYSTS [J].

DELAUDE, L ;

LASZLO, P ;

SMITH, K .

ACCOUNTS OF CHEMICAL RESEARCH, 1993, 26 (12) :607-613

[13] MILD AND SELECTIVE NITRATION BY CLAYCOP [J].

GIGANTE, B ;

PRAZERES, AO ;

MARCELOCURTO, MJ .

JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (11) :3445-3447

[14]

JACOB G, 2000, 31 INT ANN C ICT EN, V1, P106

[15] 4,10-dinitro-2,6,8,12-tetraoxa-4,10-diazaisowurtzitane (TEX):: a nitramine with an exceptionally high density [J].

Karaghiosoff, K ;

Klapötke, TM ;

Michailovski, A ;

Holl, G .

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2002, 58 (09) :O580-O581

[16] Synthesis and structures of trifluoromethyl-, fluoro-, and azido-substituted hexabenzylhexaazaisowurtzitanes and isolation of a novel hexaazaisowurtzitane-based polycycle [J].

Klapötke, TM ;

Krumm, B ;

Piotrowski, H ;

Polborn, K ;

Holl, G .

CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (03) :687-694

[17]

Klapötke TM, 2001, PROPELL EXPLOS PYROT, V26, P221, DOI 10.1002/1521-4087(200112)26:5<221::AID-PREP221>3.0.CO

[18]

2-T

[19]

KLAPOTKE TM, 1999, 30 INT ANN C ICT KAR, P120

[20]

KODAMA T, 1993, Patent No. 06321962

← 1 2 3 →