4,10-dinitro-2,6,8,12-tetraoxa-4, 10-diazaisowurtzitane(TEX)

被引：0

作者：

Bahulayan, D ^{[1
]}

Ghee, AH ^{[1
]}

机构：

[1] Nanyang Technol Univ, Energent Mat Res Ctr, Sch Mat Sci & Engn, Singapore 639798, Singapore

来源：

THEORY AND PRACTICE OF ENERGETIC MATERIALS, VOL 6 | 2005年

关键词：

4,10-dinitro-2,6,8,12-tetraoxa-4; 10-diazaisowurtzitane(TEX); nitration; 1,4-diformyl-2,3,5,6-tetrahydroxypiperazine; Glyoxal; montmorillonite K10 clay; iron(III) nitrate; clayfen; menke condition;

D O I：

暂无

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

An efficient green route for the synthesis of 4, 10-Dinitro-2, 6, 8, 12-tetraoxa4, 10-diazaisowurtzitane (TEX) (3) is developed by the nitration of a mixture of 1, 4-diformyl-2, 3, 5, 6- tetrahydroxypiperazine (1) and glyoxal solution in water (2) using montmorillonite K10 clay -supported iron (III) nitrate (Clayfen) as nitrating agent at room temperature in the presence of acetic anhydride under Menke condition.

引用

页码：11 / 14

页数：4

共 27 条

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