Facile Synthesis of MgAl-Layered Double Hydroxide Supported Metal Organic Framework Nanocomposite for Adsorptive Removal of Methyl Orange Dye

被引:60
作者
Chakraborty, Anindita [1 ]
Acharya, Himadri [1 ]
机构
[1] Assam Univ, Dept Chem, Ctr Soft Matters, Silchar 788011, Assam, India
关键词
Layered double hydroxide; Metal organic framework; Nanocomposite; Structure; Dye removal; AQUEOUS-SOLUTION; ANIONIC DYES; WASTE-WATER; NANOCRYSTALS; DEGRADATION; WASTEWATERS; NANOSHEETS; GROWTH; ZIF-8; REUSE;
D O I
10.1016/j.colcom.2018.03.005
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this work, we report the fabrication of MgAl-layered double hydroxide (LDH) supported copper based metal organic framework (MOF) nanocomposite via a facile solvothermal method. Reaction of pre-synthesized benzene-1,4-dicarboxylate ions (BDC) intercalated MgAl-LDH with Cu(II) ions produce paddle-wheel like Cu-(BDC) MOF nanocrystals on the surface of MgAl-LDHs. The structures and morphology of the synthesized new materials have been investigated by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), UV-visible and photo luminescent spectroscopy, Fourier transform infrared spectroscopy (FTIR) and thermo-gravimetric analysis (TGA). The adsorption characteristics of the synthesized material showed the dye removal efficiency over 99% after 20 min with an adsorption capacity of 600 mg/g.
引用
收藏
页码:35 / 39
页数:5
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