Bis(isoquinoline-1-carboxylato-κ2O,N)(1,10-phenanthroline-κ2N,N′)zinc(II) dimethylformamide sesquisolvate

被引：5
作者：
Daran, JC
Lemoine, P
Viossat, B
机构：
[1] Univ Paris 05, Fac Sci Pharmaceut & Biol, Lab Cristallog & RMN Biol, CNRS,UMR 8015, F-75270 Paris 06, France
[2] Chim Coordinat Lab, CNRS, UPR 8241, F-31077 Toulouse 04, France
[3] Fac Med & Pharm, Lab Chim Gen, F-86005 Poitiers, France
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2002年 / 58卷 / 04期
关键词：
D O I：
10.1107/S0108270102001932
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The asymmetric unit of the title compound, [Zn(C10H6NO2)(2)-(C12H8N2)].1.5C(3)H(7)NO, contains one monomeric zinc complex and 1.5 disordered dimethylformamide solvate molecules. The Zn atom is coordinated to one 1,10-phenanthroline ligand and to two isoquinolinecarboxylate anions (IQC(-)) via their N and O atoms. The complex exhibits a distorted octahedral geometry around the Zn-II atom, with the apical positions occupied by the O atoms of the IQC(-) ligands. The Zn atom lies 0.049 (1) Angstrom out of the basal plane. The crystal packing is characterized by several hydrogen bonds.
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页码：M210 / M212
页数：3
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