Finite step rate corrections in stress relaxation experiments: A comparison of two methods

被引:41
作者
Flory, A [1 ]
McKenna, GB [1 ]
机构
[1] Texas Tech Univ, Dept Chem Engn, Lubbock, TX 79409 USA
关键词
finite rate step; linear viscoelasticity; nonlinear viscoelasticity; stress relaxation;
D O I
10.1023/B:MTDM.0000027681.86865.4a
中图分类号
O3 [力学];
学科分类号
08 ; 0801 ;
摘要
The material response after the application of a constant strain rate ramp, followed, at time t(1), by a constant strain differs from the response to an ideal ( instantaneous) step of strain at short test times. Due to experimental limitations, the ideal step-strain cannot be achieved. As a result, short time stress relaxation data have to be corrected in order to obtain reliable estimates of, for example, the modulus G(t) at times shorter than approximately ten times the ramp time. Here we compare two methods of correction to the stress relaxation data obtained after a linear ramp, assuming a relaxation modulus of the form G(t) = G(0) e(-(t/tau)beta). The Lee and Knauss correction uses an iterative scheme based on Boltzmann superposition. We compare this method with the Zapas-Craft approach in which the 'true' relaxation time becomes t-t(1)/2 ( t is the experimental time and t(1) is the finite time to apply the step in strain). Our numerical computations show that when the relaxation time is short, there is a substantial error in the Lee-Knauss correction. Although the Zapas-Craft approach provides a better correction for times just slightly greater than t(1)/2, it is limited in that it cannot be used for times shorter than t(1)/2. We also investigate the case for which the ramp-step is replaced with a more realistic nonlinear function of time. Finally, it is often desirable to have a similar correction for large deformation responses. The Lee-Knauss method is valid only for linear viscoelastic systems whereas the Zapas-Craft approach has not been rigorously evaluated for large deformations. We evaluate the use of the latter for large deformations within the context of the Bernstein, Kearsley and Zapas single integral model.
引用
收藏
页码:17 / 37
页数:21
相关论文
共 15 条
[1]   A STUDY OF STRESS RELAXATION WITH FINITE STRAIN [J].
BERNSTEIN, B ;
KEARSLEY, EA ;
ZAPAS, LJ .
TRANSACTIONS OF THE SOCIETY OF RHEOLOGY, 1963, 7 :391-410
[2]   THERMODYNAMICS OF PERFECT ELASTIC FLUIDS [J].
BERNSTEIN, B ;
KEARSLEY, EA ;
ZAPAS, LJ .
JOURNAL OF RESEARCH OF THE NATIONAL BUREAU OF STANDARDS SECTION B-MATHEMATICAL SCIENCES, 1964, B 68 (03) :103-+
[3]  
Chang F.S.C., 1964, J APPL POLYM SCI, V8, P37, DOI 10.1002/app.1964.070080103
[4]  
DOI M, 1978, J CHEM SOC FARAD T 2, V74, P1789, DOI 10.1039/f29787401789
[5]  
Ferry D.J., 1980, Viscoelastic Properties of Polymers, V3e
[6]   MEASUREMENT OF STRESS-RELAXATION MODULUS IN PRIMARY TRANSITION REGION [J].
KELCHNER, RE ;
AKLONIS, JJ .
JOURNAL OF POLYMER SCIENCE PART A-2-POLYMER PHYSICS, 1971, 9 (04) :609-&
[7]  
KOHLRAUSCH F, 1854, POGG ANN PHYS, V140, P179
[8]   ISOBARIC VOLUME AND ENTHALPY RECOVERY OF GLASSES .2. TRANSPARENT MULTI-PARAMETER THEORY [J].
KOVACS, AJ ;
AKLONIS, JJ ;
HUTCHINSON, JM ;
RAMOS, AR .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1979, 17 (07) :1097-1162
[9]   A note on the determination of relaxation and creep data from ramp tests [J].
Lee, S ;
Knauss, WG .
MECHANICS OF TIME-DEPENDENT MATERIALS, 2000, 4 (01) :1-7
[10]   Volume and enthalpy recovery of polystyrene [J].
Simon, SL ;
Sobieski, JW ;
Plazek, DJ .
POLYMER, 2001, 42 (06) :2555-2567