Catalytic polymeric nanoreactors: more than a solid supported catalyst

被引：52

作者：

Cotanda, Pepa ^{[1
]}

Petzetakis, Nikos ^{[1
]}

O'Reilly, Rachel K. ^{[1
]}

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

MRS COMMUNICATIONS | 2012年 / 2卷 / 04期

基金：

英国工程与自然科学研究理事会;

关键词：

LIVING RADICAL POLYMERIZATION; FRAGMENTATION CHAIN TRANSFER; SELF-ASSEMBLED NANOREACTORS; BLOCK-COPOLYMER MICELLES; STAR POLYMERS; ORGANIC-SYNTHESIS; CASCADE REACTIONS; WATER; CORE; SYSTEMS;

D O I：

10.1557/mrc.2012.26

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Polymeric nanostructures can be synthesized where the catalytic motif is covalently attached within the core domain and protected from the environment by a polymeric shell. Such nanoreactors can be easily recycled, and have shown unique properties when catalyzing reactions under pseudohomogeneous conditions. Many examples of how these catalytic nanostructures can act as nanosized reaction vessels have been reported in the literature. This prospective will focus on the exclusive features observed for these catalytic systems and highlight their potential as enzyme mimics, as well as the importance of further studies to unveil their full potential.

引用

页码：119 / 126

页数：8

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