Hybrid diphosphorus ligands in rhodium catalysed asymmetric hydroformylation

被引：107
作者：
Chikkali, Samir H. [1 ,2 ]
van der Vlugt, Jarl Ivar [1 ]
Reek, Joost N. H. [1 ]
机构：
[1] Univ Amsterdam, vant Hoff Inst Mol Sci, NL-1098 XH Amsterdam, Netherlands
[2] Natl Chem Lab, Polymer Sci & Engn Div, Pune 411008, Maharashtra, India
来源：
COORDINATION CHEMISTRY REVIEWS | 2014年 / 262卷
基金：
欧洲研究理事会;
关键词：
Rhodium; Asymmetric hydroformylation; Hybrid ligand design; In situ spectroscopy; Catalyst resting state; REGIOSELECTIVE ISOMERIZATION-HYDROFORMYLATION; PHOSPHINE-PHOSPHITE LIGANDS; BITE-ANGLE; COORDINATION CHEMISTRY; INTERNAL OLEFINS; ENANTIOSELECTIVE HYDROFORMYLATION; BIDENTATE LIGANDS; SUPRAMOLECULAR CONTROL; SELECTIVE HYDROFORMYLATION; PHOSPHORAMIDITE LIGANDS;
D O I：
10.1016/j.ccr.2013.10.024
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This review aims to illustrate recent advances in the application of hybrid diphosphorus ligands for the Rh catalysed hydroformylation of alkenes, discussing the most prevalent classes of hybrid systems, i.e. phosphine-phosphinite, phosphine-phosphonite, phosphine-phosphite, phosphite-phosphoramidite and phosphite-phosphoramidite and comparing their performance with relevant C-2 symmetric counterparts. In order to introduce the field and put the results in context, a short overview on Rh hydroformylation is provided. Available spectroscopic (in situ) data on the coordination modes of hybrid phosphorus ligands and the catalytic performance of these systems in asymmetric hydroformylation of vinyl arenes are reported. Potential avenues for future research are shortly discussed. (C) 2013 Elsevier B.V. All rights reserved.
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页码：1 / 15
页数：15
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