N-doped graphene framework supported nickel cobalt oxide as supercapacitor electrode with enhanced performance

被引:43
作者
Chen, Yiying [1 ]
Liu, Tao [1 ]
Zhang, Liuyang [1 ]
Yu, Jiaguo [1 ]
机构
[1] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Luoshi Rd 122, Wuhan 430070, Hubei, Peoples R China
基金
中国国家自然科学基金;
关键词
Nickel cobalt oxide; Nanosheets; Melamine sponge; 3D nitrogen-doped graphene framework; Asymmetric supercapacitor; COMPOSITE HOLLOW MICROSPHERES; HYDROTHERMAL SYNTHESIS; FACILE SYNTHESIS; ION BATTERIES; CARBON; NITROGEN; CORE; FOAM; NANOCOMPOSITES; HYDROXIDE;
D O I
10.1016/j.apsusc.2019.04.074
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Hierarchical materials are preferred as promising electrodes due to their amply different-leveled pore channels. As one of the green, cost-effective and easy-to-synthesize materials, NiCo2O4 has fallen in the window of interest as a supercapacitor electrode material. Nevertheless, the common morphology of it, i.e. nanosheet-like architecture, is prone to be aggregated and thus leading to blocked electrochemical active sites. Herein, a glamorous structure of nickel cobalt oxide nanosheets distributed on N-doped graphene framework (NCO/NGF) has been designed. Benefiting from its unique architecture, the hybrid material delivered a specific capacitance of 1198 F g(-1) at 1 A g(-1) with an admirable long-term cycling stability. In addition, an assembled NCO/NGF\\AC device delivers much higher energy density and stability than its counterpart (NCO\\AC). The alluring performance of this composite verifies its broad application prospects as a supercapacitor electrode material.
引用
收藏
页码:135 / 143
页数:9
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