Phosphaalkene, phospholyl and phosphinine ligands: New tools in coordination chemistry and catalysis

被引：381

作者：

Le Floch, P ^{[1
]}

机构：

[1] CNRS, UMR 7653, Dept Chim Ecole Polytech, Lab Heteroelements & Coordinat, F-91128 Palaiseau, France

来源：

COORDINATION CHEMISTRY REVIEWS | 2006年 / 250卷 / 5-6期

关键词：

phosphaalkene; phosphorus derivatives; phospholide-based complexes;

D O I：

10.1016/j.ccr.2005.04.032

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review covers recent achievements in the area of low coordinate phosphorus ligands featuring P=C double bonds such as phosphaalkenes, phospholide-based complexes and phosphinines. The most significant developments are presented and discussed for each class of ligands. Particular attention has been paid to the use of these new systems as ligands in homogeneous catalysis. (c) 2005 Elsevier B.V. All rights reserved.

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页码：627 / 681

页数：55

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