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Synthesis and characterization of Ag/AgBrO3 photocatalyst with high photocatalytic activity
被引:11
|作者:
Song, Limin
[1
,2
]
Li, Tongtong
[1
,2
]
Zhang, Shujuan
[3
]
机构:
[1] Tianjin Polytech Univ, Coll Environm & Chem Engn, Tianjin 300387, Peoples R China
[2] Tianjin Polytech Univ, State Key Lab Hollow Fiber Membrane Mat & Membran, Tianjin 300387, Peoples R China
[3] Tianjin Univ Sci & Technol, Coll Sci, Tianjin 300457, Peoples R China
关键词:
Ag/AgBrO3;
semiconductor;
Photodegradation;
Rhodamine B;
(OH)-O-center dot radicals;
O-center dot(2)- radicals;
VISIBLE-LIGHT;
MECHANISM;
SEMICONDUCTOR;
IRRADIATION;
PERFORMANCE;
AG3PO4;
TIO2;
D O I:
10.1016/j.matchemphys.2016.07.012
中图分类号:
T [工业技术];
学科分类号:
08 ;
摘要:
A new Ag/AgBrO3 photocatalyst was prepared by mixing aqueous solutions of AgNO3 and NaBrO3. The catalyst's structure and performance were investigated with X-ray powder diffraction, transmission electron microscopy, and X-ray photoelectron spectroscopy. The UV-vis absorption spectrum of Ag/AgBrO3 exhibits a band gap of 3.97 eV. The results show that the Ag/AgBrO3 semiconductor can be excited by ultraviolet-visible light. The photodegradation of Rhodamine B displayed much higher photocatalytic activity than that of N-doped TiO2 under the same experimental conditions. Moreover, (OH)-O-center dot and center dot O-2(-) generated in the photocatalysis played a key role of the photodegradation of Rhodamine B. (C) 2016 Elsevier B.V. All rights reserved.
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页码:119 / 124
页数:6
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